Although ceramic solid electrolytes, such as LiLaZrO (LLZO), are promising candidates to replace conventional liquid electrolytes for developing safe and high-energy-density solid-state Li-metal batteries, the large interfacial resistance between cathodes and ceramic solid electrolytes severely limits their practical application. Here we developed an ionic liquid (IL)-containing while nonfluidic quasi-solid-state LiCoO (LCO) composite cathode, which can maintain good contact with an Al-doped LLZO (Al-LLZO) ceramic electrolyte. Accordingly the interfacial resistance between LCO and Al-LLZO was significantly decreased.
View Article and Find Full Text PDFThe increasing demand for high-energy-density batteries stimulated the revival of research interest in Li-metal batteries. The garnet-type ceramic LiLaZrO (LLZO) is one of the few solid-state fast-ion conductors that are stable against Li metal. However, the densification of LLZO powders usually requires high sintering temperatures (e.
View Article and Find Full Text PDFCharacterization and application of carbon nanosheets (CNSs) grown by microwave plasma enhanced chemical vapor deposition (MPECVD) have been investigated for the electrochemical biosensor. The as-grown CNS films possess a porous structure with a large amount of graphene edges which most of them are less than 2 nm in thickness, as confirmed by scanning and transmission electron microscopes. "Surface-sensitive" probe, Fe(CN)(6)(3-/4-), exhibits that the original CNSs have faster electron transfer than glassy carbon electrode, owing to much more edge plane sites on the original CNS surface.
View Article and Find Full Text PDFThe bare Pt electrode modified directly and simply by carbon nanosheets, which were synthesized by microwave plasma enhanced chemical vapor deposition at relatively low temperature, can be used to simultaneously and effectively detect dopamine, ascorbic acid and uric acid.
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