Recent progress in high-voltage P2-Na TMO materials and their future perspectives.

P2-type layered materials (Na TMO) have become attractive cathode electrodes owing to their high theoretical energy density and simple preparation. However, they still face severe phase transition and low conductivity. Current research on Na TMO is mostly focused on the modification of bulk materials, and the application performances have been infrequently addressed.

Circularly polarized blue fluorescence based on chiral heteroleptic six-coordinate -pyrazolonate-Zn complexes.

Applying molecular design to chiral organo-Zn complexes, a new pair of chiral heteroleptic -pyrazolonate-Zn enantiomers [Zn(PMBP)(1,2-Chxn)] (R,R-Zn2+; HPMBP = 1-phenyl-3-methyl-4-benzoyl-5-pyrazolone and 1R,2R-Chxn = (1,2)-cyclohexane-1,2-diamine) and [Zn(PMBP)(1,2-Chxn)] (S,S-Zn2+; 1S,2S-Chxn = (1,2)-cyclohexane-1,2-diamine) have been synthesized and characterized in terms of photophysical and thermodynamic properties. In addition to a small Flack parameter (0.05(3)) associated with the solid-state elucidation of S,S-Zn2+, the circular dichroism (CD) and circularly polarized light (CPL) spectra for the chiral Zn enantiomers show perfect mirror symmetry, establishing that the enantiopure 1,2-diamines successfully induce the optical isomerism of R,R-Zn2+ and S,S-Zn2+.

Gamma-Glutamyl Transpeptidase-to-Platelet ratio predicts liver fibrosis in patients with concomitant chronic hepatitis B and nonalcoholic fatty liver disease.

Objectives: The aim of this study was to compare the correlation of gamma-glutamyl transpeptidase-to-platelet ratio (GPR), aspartate aminotransferase-to-platelet ratio index (APRI), fibrosis index-4 (FIB-4), and liver stiffness measurement (LSM) in the diagnosis of liver fibrosis, and perform a diagnostic value of GPR for predicting fibrosis in CHB patients with NAFLD.

Methods: A retrospective study was conducted on CHB patients concurrent with NAFLD between September 2019 and December 2020. They were divided into control group (LSM ≤ 9.

Synergistically reinforced poly(ethylene oxide)-based composite electrolyte for high-temperature lithium metal batteries.

Traditional liquid lithium-ion batteries are not applicable for extreme temperatures, due to the shrinkage of separators and volatility of electrolytes. It is necessary to develop advanced electrolytes with desirable characteristics in terms of thermal stability, electrochemical stability and mechanical properties. Solid-state electrolytes, such as polyethylene oxide (PEO), outperform other types and bring the opportunity to realize the high-temperature lithium-ion batteries.

Porosity Tunable Poly(Lactic Acid)-Based Composite Gel Polymer Electrolyte with High Electrolyte Uptake for Quasi-Solid-State Supercapacitors.

The growing popularity of quasi-solid-state supercapacitors inevitably leads to the unrestricted consumption of commonly used petroleum-derived polymer electrolytes, causing excessive carbon emissions and resulting in global warming. Also, the porosity and liquid electrolyte uptake of existing polymer membranes are insufficient for well-performed supercapacitors under high current and long cycles. To address these issues, poly(lactic acid) (PLA), a widely applied polymers in biodegradable plastics is employed to fabricate a renewable biocomposite membrane with tunable pores with the help of non-solvent phase inversion method, and a small amount of poly (vinylidene fluoride-co-hexafluoropropylene) (PVDF-HFP) is introduced as a modifier to interconnect with PLA skeleton for stabilizing the porous structure and optimizing the aperture of the membrane.

Supramolecular-induced 2.40 V 130 °C working-temperature-range supercapacitor aqueous electrolyte of lithium bis(trifluoromethanesulfonyl) imide in dimethyl sulfoxide-water.

Increasing the electrochemical stability window and working temperature range of supercapacitor aqueous electrolyte is the major task in order to advance aqueous electrolyte-based supercapacitors. Here, a supramolecular induced new electrolyte of lithium bis(trifluoromethanesulfonyl) imide (LiTFSI) in dimethyl sulfoxide (DMSO) and water co-solvent system is proposed. Adjusting the coordination structure among LiTFSI, DMSO, and water in the electrolyte via supramolecular interactions results in its high ionic conductivity, low viscosity, wide electrochemical stability window, and large working temperature range.

Antimony nanocrystals self-encapsulated within bio-oil derived carbon for ultra-stable sodium storage.

Integrating carbon-coating and nanostructuring has been considered as the most promising strategy to accommodate the dramatic volume expansion represented by high-capacity antimony (Sb) upon sodiation. Suitable coating source and synthetic strategy that are both economical and strong are yet to be explored. In this regard, by using renewable bio-oil as carbon source and self-wrapping precursor, robust Sb@C composite anode with Sb nanoparticles homogeneously impregnated into the cross-linked 2D ultrathin carbon nanosheets is developed via a facile NaCl template-assisted self-assembly and followed carbothermal reduction method.

Novel Polyimide Separator Prepared with Two Porogens for Safe Lithium-Ion Batteries.

A porous polyimide (PI) membrane is successfully prepared via nonsolvent-induced phase separation with two porogens: dibutyl phthalate and glycerin. The as-prepared uniform porous PI membrane shows excellent separator properties for lithium-ion batteries (LIBs). Compared with the commercial polyethylene (PE) separator, the PI separator exhibits significant thermal stability, better ionic conductivity, and wettability both in carbonate and ether electrolytes for LIBs.