Boosting Dimethyl Carbonate Production from CO and Methanol using Ceria-Ionic Liquid Catalyst.

As a crucial strategy towards a sustainable chemical industry, the direct synthesis of dimethyl carbonate (DMC) from renewable carbon dioxide (CO) and methanol (MeOH) is studied using CeO nanoparticles modified with 1-butyl-3-methylimidazolium hydrogen carbonate ([BMIm][HCO]) devoid of stoichiometric dehydrating agents. The synthesized CeO@[BMIm][HCO] catalyst having high thermal stability harnesses the unique physicochemical properties of CeO and the ionic liquid to exhibit a DMC yield of 10.4 % and a methanol conversion of 16.

Experimental study of cross-flow wet electrostatic precipitator.

Unlabelled: This paper reports development and testing of a novel cross-flow wet electrostatic precipitator (WESP), recently patented at Ohio University, that utilizes vertical columns of permeable material in the form of polypropylene ropes placed in a cross-flow configuration within a flue gas stream. The cross-flow design has large surface area, which provides scrubbing action; therefore, it has the potential for removing multiple pollutants, including particulates, gases, vapors, and mists. In this new method, the ropes are kept wet by the liquid (water) introduced from the top of the cells running downward on the ropes by capillary action, making the permeable materials act as the ground electrode for capturing particles from the flue gas.

The magnetic moment enigma in Fe-based high temperature superconductors.

The determination of the most appropriate starting point for the theoretical description of Fe-based materials hosting high-temperature superconductivity remains among the most important unsolved problem in this relatively new field. Most of the work to date has focused on the pnictides, with LaFeAsO, BaFe(2)As(2) and LiFeAs being representative parent compounds of three families known as 1111, 122 and 111, respectively. This topical review examines recent progress in this area, with particular emphasis on the implication of experimental data which have provided evidence for the presence of electron itinerancy and the detection of local spin moments.

Origins of electronic band gap reduction in Cr/N codoped TiO2.

Recent studies indicated that noncompensated cation-anion codoping of wide-band-gap oxide semiconductors such as anatase TiO2 significantly reduces the optical band gap and thus strongly enhances the absorption of visible light [W. Zhu et al., Phys.

Universal versus material-dependent two-gap behaviors of the high-Tc cuprate superconductors: angle-resolved photoemission study of La2-xSrxCuO4.

We have investigated the doping and temperature dependences of the pseudogap and superconducting gap in the single-layer cuprate La2-xSrxCuO4 by angle-resolved photoemission spectroscopy. The results clearly exhibit two distinct energy and temperature scales, namely, the gap around (pi, 0) of magnitude Delta* and the gap around the node characterized by the d-wave order parameter Delta0. In comparison with Bi2212 having higher Tc's, Delta0 is smaller, while Delta* and T* are similar.

Evidence for strong itinerant spin fluctuations in the normal state of CeFeAsO0.89F0.11 iron-oxypnictide superconductors.

The electronic structure in the normal state of CeFeAsO0.89F0.11 oxypnictide superconductors has been investigated with x-ray absorption and photoemission spectroscopy.

Monochromatic electron photoemission from diamondoid monolayers.

We found monochromatic electron photoemission from large-area self-assembled monolayers of a functionalized diamondoid, [121]tetramantane-6-thiol. Photoelectron spectra of the diamondoid monolayers exhibited a peak at the low-kinetic energy threshold; up to 68% of all emitted electrons were emitted within this single energy peak. The intensity of the emission peak is indicative of diamondoids being negative electron affinity materials.

Energy dispersion of 4f-derived emissions in photoelectron spectra of the heavy-fermion compound YbIr2Si2.

Angle-resolved photoemission spectra of the heavy-fermion system YbIr(2)Si(2) are reported that reveal strong momentum (k) dependent splittings of the 4f(13) bulk and surface emissions around the expected intersection points of the 4f final states with valence bands in the Brillouin zone. The obtained dispersion is explained in terms of a simplified periodic Anderson model by a k dependence of the electron hopping matrix element disregarding clearly interpretation in terms of a single-impurity model.

Nodal quasiparticle in pseudogapped colossal magnetoresistive manganites.

A characteristic feature of the copper oxide high-temperature superconductors is the dichotomy between the electronic excitations along the nodal (diagonal) and antinodal (parallel to the Cu-O bonds) directions in momentum space, generally assumed to be linked to the 'd-wave' symmetry of the superconducting state. Angle-resolved photoemission measurements in the superconducting state have revealed a quasiparticle spectrum with a d-wave gap structure that exhibits a maximum along the antinodal direction and vanishes along the nodal direction. Subsequent measurements have shown that, at low doping levels, this gap structure persists even in the high-temperature metallic state, although the nodal points of the superconducting state spread out in finite 'Fermi arcs'.

Multiple bosonic mode coupling in the electron self-energy of (La2-xSrx)CuO4.

High resolution angle-resolved photoemission spectroscopy data along the (0,0)-(pi,pi) nodal direction with significantly improved statistics reveal fine structure in the electron self-energy of the underdoped (La2-xSrx)CuO4 samples in the normal state. Fine structure at energies of (40-46) meV and (58-63) meV, and possible fine structure at energies of (23-29) meV and (75-85) meV, have been identified. These observations indicate that, in (La2-xSrx)CuO4, more than one bosonic modes are involved in the coupling with electrons.

Direct observation of high-temperature polaronic behavior in colossal magnetoresistive manganites.

The temperature dependence of the electronic and atomic structure of the colossal magnetoresistive oxides La1-xSrxMnO3 (x=0.3, 0.4) has been studied using core and valence level photoemission, x-ray absorption and emission, and extended x-ray absorption fine structure spectroscopy.