Nonconjugated amylopectin-grafted copolymers with dual fluorescence/low-temperature phosphorescence emission and superior processability.

Nonconjugated fluorescent polymers devoid of large π-π conjugated structures have received considerable attention due to their significant academic importance and broad application potentials in various fields. Herein, we report an effective strategy to fabricate multifunctional fluorescent amylopectin derivatives and reveal their unique aspects of aggregation-induced emission (AIE), cryogenic long-persistent phosphorescence (~6 s) and excellent processabilities characteristics, which are extremely different from traditional luminogens. These amylopectin-graft-poly(n-butyl acrylate-co-1-vinylimidazole) copolymers (Amylopectin-BVs) prepared by the grafting-from method employing RAFT and experienced subsequently with metal-ligand cross-linking.

Synthesization and Characterization of Lignin-graft-Poly (Lauryl Methacrylate) via ARGET ATRP.

Lignin as an abundant biological macromolecule isolated from the plant cell wall, and it cannot be efficiently utilized until suitable modifications to its structures were made. Therefore, we proposed a strategy to prepare an all biomass-based Lignin-graft-poly(Lauryl methacrylate, LMA) by grafting LMA monomers on the organosolv lignin through ARGET ATRP. The results of FT-IR and H NMR analysis demonstrated that PLMA molecular chains were successfully grafted on the lignin.