Sustainable valorization of agricultural waste into bioplastic and its end-of-life recyclability for biochar production: Economic profitability and life cycle assessment.

While the industrial sectors have recently focused on producing bioplastic materials, the utilization of edible feedstocks and the generation of wastes and byproducts during the bioplastic synthesis process might delay achieving the environmental sustainability strategy. To overcome these limitations related to bioplastic industrialization, this study focuses on synthesizing bioplastics from waste sources, followed by recycling its end-of-life (e.g.

Illuminating bioprocess responses to metal-based nanoparticles addition along hydrogen and methane production pathways: A review.

Recent research has discussed the positive impacts of metal-based nanoparticles (NPs) on bioprocesses producing either hydrogen (H) or methane (CH). The enhancement has been explained by mechanisms such as direct interspecies electron transfer (DIET), metal corrosion, and dissimilatory reduction. Such interactions could induce further benefits, such as controlling oxidation-reduction potential (ORP), mitigating toxicants, promoting enzymatic activity, and altering the microbiome, which have not yet been comprehensively discussed.

Incorporating concrete waste as additive in acidic fermentation-A novel approach for enhanced biohydrogen production and concrete mass reduction.

Acidic fermentation (AF) of organic waste/wastewater generates valuable byproducts, including hydrogen, volatile fatty acids, and ethanol; however, its sensitivity to pH drops limits the stability and efficiency of the process. A reversal process, the acidic chemical treatment of concrete waste (CW) to recycle its aggregates, generates calcium hydroxide, which can serve as buffering agent. Meanwhile, integrating both processes can introduce a sustainable win-win approach, which is the aim of this study.

Thermodynamics and explainable machine learning assist in interpreting biodegradability of dissolved organic matter in sludge anaerobic digestion with thermal hydrolysis.

Dissolved organic matter (DOM) is essential in biological treatment, yet its specific roles remain incompletely understood. This study introduces a machine learning (ML) framework to interpret DOM biodegradability in the anaerobic digestion (AD) of sludge, incorporating a thermodynamic indicator (λ). Ensemble models such as Xgboost and LightGBM achieved high accuracy (training: 0.

utilization for dual phytoremediation and adsorption in greywater treatment: a techno-economic and sustainable approach.

While phytoremediation has been widely employed for greywater treatment, this system suffers from the transfer of considerable amounts of surfactants to the aquatic environment through partially treated effluent and/or exhausted plant disposal. Hence, this study focuses on greywater phytoremediation followed by recycling the spent plant for preparing an adsorbent material used as post-treatment. was used to operate a phytoremediation unit under 23 °C, 60% relative humidity, plant density (5-30 g/L), dilution (0-50%), pH (4-10), and retention time (3-15 days).

Insight into the mechanism of chlorinated nitroaromatic compounds anaerobic reduction with mackinawite (FeS) nanoparticles.

Anaerobic biotechnology for wastewaters treatment can nowadays be considered as state of the art methods. Nonetheless, this technology exhibits certain inherent limitations when employed for industrial wastewater treatment, encompassing elevated substrate consumption, diminished electron transfer efficiency, and compromised system stability. To address the above issues, increasing interest is being given to the potential of using conductive non-biological materials, e,g.

Photo-production of excited triplet-state of dissolved organic matters in inland freshwater and coastal seawater.

The excited triplet-state of dissolved organic matter (DOM*) is a major reactive intermediate in sunlit waters. Its quantum yield is important in understanding the fate of organic micropollutants. The degradation efficiency of its chemical probe, 2,4,6-trimeythlphenol (f), is generally used as a proxy of the quantum yield.

FT-ICR MS Spectral Improvement of Dissolved Organic Matter by the Absorption Mode: A Comparison of the Electrospray Ionization in Positive-Ion and Negative-Ion Modes.

Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR MS) in the absorption mode has a superior performance over the conventional magnitude mode. However, this improved performance for the analysis of dissolved organic matter (DOM) in negative-ion and positive-ion modes of electrospray ionization [ESI(-) and ESI(+), respectively] remains unknown. This study systemically compared the improved performance by the absorption mode for DOM FT-ICR MS spectra acquired with the low-field and high-field magnet instruments between two charge modes.

Interpretable Machine Learning and Reactomics Assisted Isotopically Labeled FT-ICR-MS for Exploring the Reactivity and Transformation of Natural Organic Matter during Ultraviolet Photolysis.

Isotopically labeled FT-ICR-MS combined with multiple post-analyses, including interpretable machine learning (IML) and a paired mass distance (PMD) network, was employed to unravel the reactivity and transformation of natural organic matter (NOM) during ultraviolet (UV) irradiation. FT-ICR-MS analysis was used to assign formulas, which were classified on the basis of their molecular compositions and structural categories. Isotope (deuterium, D) labeling was utilized to unequivocally determine the photochemical products and examine the development of OD radical-mediated NOM transformation.

Characterization of halogenated organic compounds by the Fourier transform ion cyclotron resonance mass spectrometry: A critical review.

Halogenated organic compounds (HOCs), widely present in various environments, are generally formed by natural processes (e.g., photochemical halogenation) and anthropogenic activities (e.

Apparent quantum yield for photo-production of singlet oxygen in reservoirs and its relation to the water matrix.

Man-made reservoirs are important for human daily lives and offer different functions, however they are contaminated due to anthropogenic activities. Dissolved organic matter (DOM) from each reservoir is unique in composition, which further determines its photo-reactivity. Thus, this study aimed to investigate the photo-reactivity of reservoir DOM in terms of the quantum yield for photo-production of singlet oxygen (Ф).

Bioelectrochemical system for enhancing anaerobic digestion of pharmaceutical-containing domestic wastewater.

The unprecedented recent expansion in usage of paracetamol (AAP) has increased the need for suitable wastewater treatment technology. Furthermore, direct interspecies electron transfer promotion (DIET) offers simple and efficient approach for enhancing anaerobic digestion (AD). In this work, using AAP-containing domestic wastewater as feed, control AD reactor (RC) was operated, besides three DIET-promoted AD reactors (REV, RMC and REVMC, referring to electrical voltage "EV"-applied, nFeO-multiwall carbon nanotube (MCNT)-supplemented, and "EV applied + MCNT supplemented" reactor, respectively).

Complementary Elucidation of the Molecular Characteristics of Groundwater Dissolved Organic Matter Using Ultrahigh-Resolution Mass Spectrometry Coupled with Negative- and Positive-Ion Electrospray Ionization.

The formula assignment of the Fourier transform ion cyclotron resonance mass spectrometry coupled with positive-ion electrospray ionization [ESI(+)-FT-ICR MS] is challenging because of the extensive occurrence of adducts. However, there is a paucity of automated formula assignment methods for ESI(+)-FT-ICR MS spectra. The novel automated formula assignment algorithm for ESI(+)-FT-ICR MS spectra developed herein has been applied to elucidate the composition of dissolved organic matter (DOM) in groundwater during air-induced ferrous [Fe(II)] oxidation.

Development of a Gaussian-Based Alignment Algorithm for the Ultrahigh-Resolution Mass Spectra of Dissolved Organic Matter.

The alignment of ultrahigh-resolution mass spectra (UHR-MS) is critical to inspect the presence of unique and common peaks across multiple UHR-MS spectra. However, few attempts have been conducted to develop an automated alignment method. In this study, a novel automated alignment algorithm, namely, FTMSCombine, that follows a Gaussian distribution of mass errors was developed and then integrated with existing FTMSCalibrate and TRFu algorithms to establish an open-source analysis platform, namely, FTMSAnalysis, for the UHR-MS analysis of the dissolved organic matter.

Effective decontamination of methylene blue from aqueous solutions using novel nano-magnetic biochar from green pea peels.

The conversion of agricultural waste into high-value carbon products has been an attractive area in waste management strategy. This study highlighted the synthesis and effectiveness of green pea peels (GPP), green pea biochar (GPBC), and nano-ferromagnetic green pea biochar (NFGPBC) by the ferrous/ferric co-precipitation synthesis method for eliminating cationic dyes molecules from solutions. The morphological, physicochemical, and structural properties of GPP, GPBC, and NFGPBC were approved by Scanning Electron Microscopy (SEM), Transmission Emission Microscopy (TEM), Energy Dispersive X-ray (EDX), Bruneau Emmett Teller (BET), Fourier Transform Infrared spectroscopy (FTIR), and X-ray Diffraction (XRD) techniques.

Comprehensive understanding of DOM reactivity in anaerobic fermentation of persulfate-pretreated sewage sludge via FT-ICR mass spectrometry and reactomics analysis.

Understanding the composition and reactivity of dissolved organic matter (DOM) at molecular level is vital for deciphering potential regulators or indicators relating to anaerobic process performance, though it was hardly achieved by traditional analyses. Here, the DOM composition, molecular reactivity and transformation in the enhanced sludge fermentation process were comprehensively elucidated using high-resolution mass spectrometry measurement, and data mining with machine learning and paired mass distance (PMD)-based reactomics. In the fermentation process for dewatered sludge, persulfate (PDS) pretreatment presented its highest performance in improving volatile fatty acids (VFAs) production with the increase from 2,711 mg/L to 3,869 mg/L, whereas its activation in the presence of Fe (as well as the hybrid of Fe and activated carbon) led to the decreased VFAs production performance.

Preliminary quantitative assessment of the multidimensional impact of the COVID-19 pandemic on Sustainable Development Goals.

The intersectoral impacts of the COVID-19 pandemic on humanity raises concerns about its implications for sustainable development. Here, we examine a global quantitative impact of COVID-19 pandemic on Sustainable Development Goals (SDGs) across all 17 goals using 65 proxy indicators across 72 countries collected from April 2020 to February 2021. Our data-driven analysis indicated that adverse impacts of the pandemic have been particularly concerned on gender equality (Goal 5), affordable and clean energy (Goal 7), decent work and economic growth (Goal 8), sustainable cities and communities (Goal 11), and responsible consumption and production (Goal 12) with global scores estimated to be -0.

Phytomanagement of textile wastewater for dual biogas and biochar production: A techno-economic and sustainable approach.

Phytoremediation has been widely employed for industrial effluent treatment due to its cost-effectiveness and eco-friendliness. However, this process generates large amounts of exhausted plant biomass, requiring appropriate management strategies to avoid further environmental pollution. To the best of the authors' knowledge, this study is the first to address the recyclability of water hyacinth after textile wastewater (TWW) phytoremediation for dual biogas and biochar production.

Development of an Internal Calibration Algorithm for Ultrahigh-Resolution Mass Spectra of Dissolved Organic Matter.

In order to obtain a spectrum with high mass accuracy, an internal calibration of Fourier transform ion cyclotron resonance mass spectrometry (FTICR-MS) is inevitable. This in turn is critical for subsequent data processing and is generally performed using the commercial instrument software DataAnalysis in the benchmark calibration mode. However, no methodological study has systemically addressed the automated internal calibration of FTICR-MS spectra for dissolved organic matter (DOM) from different sources such as terrestrial and aquatic environments.

Facile synthesis of broom stick like FeOCl/g-CN nanocomposite as novel Z-scheme photocatalysts for rapid degradation of pollutants.

A simple and cost-effective route has been utilized for the preparation of a novel lamellar structured FeOCl/g-CN nanocomposite as Z-scheme photocatalyst. The preparation method was performed under the ambient temperature conditions without any hazardous chemicals. Various characterization techniques, namely XRD, FESEM, TEM, FT-IR, UV-Vis, DRS, and PL were carried out to analyse the nanocomposite for confirmation of FeOCl/g-CN nanocomposite.

Novel S-scheme 2D/2D BiOBr nanoplatelets/g-CN heterojunctions with enhanced photocatalytic activity towards organic pollutants removal.

Removal of organic pollutants and pharma products in waste water using semiconductor photocatalysts has gained huge interest among recent days. However, low visible light absorption, recombination rate of charge carriers and less availability of reaction sites are still major obstacles for the photocatalysis process. Herein, an in situ-forming BiOBr nanosheets decorated on the surface g-CN were prepared via simple hydrothermal method under ambient temperature.

Heavy metal remediation from wastewater using microalgae: Recent advances and future trends.

Microalgae-based wastewater treatment has previously been carried out in huge waste stabilization ponds. Microalgae, which can absorb carbon dioxide while reusing nutrients from sewage, has recently emerged as a new trend in the wastewater treatment business. Microalgae farming is thought to be a potential match for the modern world's energy strategy, which emphasizes low-cost and environmentally benign alternatives.

Unraveling the metabolic shift in anaerobic digestion pathways associated with the alteration of onion skin waste concentration.

Onion skin waste (OSW) is common waste in developing countries, which can cause severe environmental pollution when not properly treated. Value-added products can be chemically extracted from OSW; however, that process is not economically feasible. Alternatively, dry anaerobic digestion (DAD) of OSW is a promising approach for both energy recovery and environment protection.