IntraPD model: Leaching of heavy metals from naturally contaminated soils.

This paper presents a novel method for predicting the migration of heavy metal contaminants in soils that contain heavy metal pollutants deep within the particles, which may cause delayed leaching. The proposed approach, the intraparticle pore-diffusion (IntraPD) model, incorporates both intraparticle diffusion and sorption equilibrium and is utilized to simulate batch leaching tests of heavy metal-contaminated soils using the finite difference method. The IntraPD model can solve the leakage of heavy metals from contaminated soil particles of arbitrary particle size distribution as a one-dimensional, polar-symmetric problem in the spherical coordinate system, assuming the soil particles to be porous perfect spheres.

New concept to describe three-phase capillary pressure-degree of saturation relationship in porous media.

The Leverett concept is used conventionally to model the relationship between the capillary pressures and the degrees of saturation in the water-nonaqueous phase liquid (NAPL)-air three-phase system in porous media. In this paper, the limitation of the Leverett concept that the concept is not applicable in the case of nonspreading NAPLs is discussed through microscopic consideration. A new concept that can be applied in the case of nonspreading NAPLs as well as spreading NAPLs is then proposed.