This work presents the effect of CeO nanoparticles (CeO-NPs) on Cu-50Ni-5Al alloys on morphological, microstructural, degradation, and electrochemical behavior at high temperatures. The samples obtained by mechanical alloying and spark plasma sintering were exposed to a molten eutectic mixture of LiCO-KCO for 504 h. The degradation of the materials was analyzed using gravimetry measurements and electrochemical impedance spectroscopy.
View Article and Find Full Text PDFThis research aims to examine how a radial graded porosity distribution affects the elastic modulus by conducting simulations on Ti-based alloy foams with face-centered cubic and body-centered cubic crystal structures. Four types of foams were analyzed; commercially pure-Ti, Ti-13Ta-6Mn (TTM), Ti-13Ta-(TT) and Ti-13Ta-6Sn (TTS), (all in at.%).
View Article and Find Full Text PDFFuel cell technology has developed due to diminishing dependence on fossil fuels and carbon footprint production. This work focuses on a nickel-aluminum bronze alloy as an anode produced by additive manufacturing as bulk and porous samples, studying the effect of designed porosity and thermal treatment on mechanical and chemical stability in molten carbonate (LiCO-KCO). Micrographs showed a typical morphology of the martensite phase for all samples in as-built conditions and a spheroid structure on the surface after the heat treatment, possibly revealing the formation of molten salt deposits and corrosion products.
View Article and Find Full Text PDFClimate change has evidenced the need to reduce carbon dioxide emissions into the atmosphere, and so for transport applications, lighter weight alloys have been studied, such as magnesium alloys. However, they are susceptible to corrosion; therefore, surface treatments have been extensively studied. In this work, the influence of argon plasma pretreatment on the surface properties of an AZ31 magnesium alloy focus on the enhancement of the reactivity of the surface, which was examined by surface analysis techniques, electrochemical techniques, and gravimetric measurements.
View Article and Find Full Text PDFIn this study, the effect of the recycling process and copper particle incorporation on virgin and recycled pellet HDPE were investigated by thermo-chemical analysis, mechanical characterization, and antibacterial analysis. Copper particles were added to pellet HDPE, virgin and recycled, using a tabletop single screw extruder. Some copper particles, called copper nano-particles (Cu-NPs), had a spherical morphology and an average particle size near 20 nm.
View Article and Find Full Text PDFThe increase in longevity worldwide has intensified the use of different types of prostheses for the human body, such as those used in dental work as well as in hip and knee replacements. Currently, Ti-6Al-4V is widely used as a joint implant due to its good mechanical properties and durability. However, studies have revealed that this alloy can release metal ions or particles harmful to human health.
View Article and Find Full Text PDFIn this work, electrochemical techniques were employed to evaluate the contribution to the corrosion and corrosion inhibition of 2024-T3 aluminum alloy by two Gram-positive bacteria. In addition, polarized impedance was used to determine the microbial effect on the cathodic and anodic reactions. These microorganisms were collected from a tropical environment due to the favorable bacterial growth of this kind of climate.
View Article and Find Full Text PDFTi-6Al-4V alloy has been widely investigated for biomedical applications due to its low density, high specific strength, and favorable corrosion resistance. However, some reported failures have imposed a challenge to improve bone regeneration and fixation, as well as antibacterial properties. A further opportunity for solving this problem is the introduction of porosity.
View Article and Find Full Text PDFThe tribological properties of a novel porous Ti-Nb-Ta-Fe-Mn alloy with 0%, 30%, and 60% porosity were evaluated for biomedical applications. The tribotesting was performed using a ball-on-disc under dry conditions, using an alumina ball and 1 N of a load. The coefficient of friction at the early stage of the porous samples was lower than that of the bulk, 0.
View Article and Find Full Text PDFMater Sci Eng C Mater Biol Appl
June 2020
Porous titanium materials have gained interest as prosthesis materials due to their similar mechanical properties to the human bone, biocompatibility, and high corrosion resistance. The presence of pores in the metal matrix implies a decrease in the elastic modulus and an increase in the active area, perhaps improving the osseointegration. Corrosion resistance is a critical consideration as corrosion may lead not only to mechanical failure but also the release of ions and/or particles to the bloodstream.
View Article and Find Full Text PDFCommon alloys used for the manufacture of aircrafts are subject to different forms of environmental deterioration. A major one is corrosion, and there is a strong body of evidence suggesting that environmental microorganisms initiate and accelerate it. The development of an appropriate strategy to reduce this process depends on the knowledge concerning the factors involved in corrosion.
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