The effect of an acidic environment during the hydrothermal carbonization of sewage sludge on solid and liquid products: The fate of heavy metals, phosphorus and other compounds.

The pH of sewage sludge is a crucial factor during the hydrothermal carbonization process that influences the characteristics of the resulting products and migration of certain compounds from the solid to liquid phase. Accordingly, this work is focused on examining the pH impact during the HTC process, in particular, pH equals 2, 3, 4, 5 and 6 on the individual hydrothermally carbonized products generated at 200 °C and 2 h residence time. For this reason, the chemical and physical indicators describing the post-processing liquid and hydrochar were determined.

NGS analysis of collagen type I genes in Polish patients with Osteogenesis imperfecta: a nationwide multicenter study.

Osteogenesis imperfecta (OI) is a rare genetic disorder of the connective tissue. It presents with a wide spectrum of skeletal and extraskeletal features, and ranges in severity from mild to perinatal lethal. The disease is characterized by a heterogeneous genetic background, where approximately 85%-90% of cases have dominantly inherited heterozygous pathogenic variants located in the and genes.

The effect of an acid catalyst on the hydrothermal carbonization of sewage sludge.

This research is focused on the addition of a catalyst, sulphuric acid (VI), to sewage sludge, and its effect on solid and liquid products resulting from the hydrothermal carbonization process. Consequently, for hydrochars, proximate and ultimate analyses, higher heating value and specific surface area were determined. Additionally, Fourier-transform infrared spectrophotometric and thermogravimetric analyses were conducted.

Life cycle assessment of the hydrothermal carbonization process applied to the wet fraction mechanically separated from municipal mixed waste.

The under-sieve fraction (USF), obtained as one of the output streams from the mechanical pretreatment of mixed municipal solid waste, is usually aerobically biologically stabilized before being landfilled. For its characteristics (i.e.

The Utilisation of Solid Fuels Derived from Waste Pistachio Shells in Direct Carbon Solid Oxide Fuel Cells.

The comprehensive results regarding the physicochemical properties of carbonaceous materials that are obtained from pistachio shells support their usage as solid fuels to supply direct carbon solid oxide fuel cells (DC-SOFCs). The influence of preparation conditions on variations in the chemical composition, morphology of the biochar powders, and degree of graphitization of carbonaceous materials were investigated. Based on structural investigations (X-ray diffraction analysis and Raman spectroscopy), it was observed that disordered carbon particles developed during the application of thermal treatments.

Effect of SWCNT-Tuball Paper on the Lightning Strike Protection of CFRPs and Their Selected Mechanical Properties.

The main aim of this work was the investigation of the possibility of replacing the heavy metallic meshes applied onto the composite structure in airplanes for lightning strike protection with a thin film of Tuball single-wall carbon nanotubes in the form of ultra-light, conductive paper. The Tuball paper studied contained 75 wt.% or 90 wt.

Combustion and kinetic parameters estimation of torrefied pine, acacia and Miscanthus giganteus using experimental and modelling techniques.

A novel approach, linking both experiments and modelling, was applied to obtain a better understanding of combustion characteristics of torrefied biomass. Therefore, Pine, Acacia and Miscanthus giganteus have been investigated under 260°C, 1h residence time and argon atmosphere. A higher heating value and carbon content corresponding to a higher fixed carbon, lower volatile matter, moisture content, and ratio O/C were obtained for all torrefied biomass.

Assessment of selected lipid parameters in in children exposed to gestational diabetes (GDM) in utero.

Introduction: The assessment of maternal hyperglycemia during pregnancy and lipid profile in the offspring is recently highlighted.

Aim: The study was undertaken to assess the selected lipid parameters in children exposed to gestational diabetes (GDM) in utero.

Material And Methods: 50 children, 7-15 years of age, exposed to GDM were compared with 46 control subjects (7-16 years old).

Assessment of selected carbohydrate parameters in children exposed to gestational diabetes in utero.

Objectives: The study was undertaken to assess the selected carbohydrate parameters in children exposed to gestational diabetes in utero.

Methods: 50 children exposed to gestational diabetes were compared with 46 control subjects. Anthropometric parameters of a newborn were obtained from the medical records.

[Assessment of selected anthropometric parameters in children exposed to gestational diabetes in utero - preliminary results].

Introduction: Current studies show uncreased risk of obesity cardiovascular diseases and diabetes mellitus in children exposed to gestational diabetes in utero.

Aim: The aim of this study was to assess the selected anthropometric parameters in children exposed to gestational diabetes in utero.

Material And Methods: 43 children, 7-15 years of age, exposed to gestational diabetes in utero were included in the study.

The significance of molecular studies in the long-term follow-up of children with beckwith- wiedemann syndrome.

Beckwith-Wiedemann syndrome (BWS) is a congenital disorder of imprinting caused by epimutations and mutations affecting two imprinted loci on chromosome 11p15. Its clinical features are heterogeneous, including macrosomia, macroglossia, hemihyperplasia, abdominal wall defects, neonatal hypoglycemia, and increased risk of embryonal tumors such as Wilms tumor, adrenocortical carcinoma, hepatoblastoma, and neuroblastoma. The molecular and clinical heterogeneity of BWS makes the diagnosis challenging, but essential, since different etiologies of BWS have different clinical prognoses - most crucially, patients with gain of maternal methylation at imprinting control region type 1 (ICR1) are at significant risk of Wilms tumor or hepatoblastoma.

The impact of short-term cardiac rehabilitation on changing dietary habits in patients after acute coronary syndrome.

Purpose: The aim of this study was to determine whether short-term cardiac rehabilitation (CR), including dietary counseling, had an impact on changing eating habits in patients after acute coronary syndrome (ACS), treated with primary percutaneous coronary intervention (PCI).

Methods: The controlled, prospective, nonrandomized study was performed on 44 patients, early following ACS/PCI, who underwent 2- to 3-week inpatient CR with dietary counseling and compared to 18 patients who did not participate in CR. An analysis of the daily diet composition was performed at baseline, at 3 months post-ACS, and at 1 year post-ACS.

Analysis of biologically active peptides using two-dimensional HPLC-CE.

High-performance liquid chromatography (HPLC) is a technique most frequently used for the assessment of biologically active peptides. Owing to the ionic character of these compounds, they may also be separated and assayed using capillary electrophoresis (CE), which offers very high efficiency, short analysis time and low consumption of reagents, and is used increasingly more often. The paper describes the combination of HPLC and CE in order to increase the efficiency of the separation of complex mixture of peptides (active substance and its related impurities).

New approach for amino acid profiling in human plasma by selective fluorescence derivatization.

A new approach for the separation of 6-aminoquinolyl-carbamyl (AQC)-derivatized amino acids has been proposed. The chromatography used ion-pairing mechanism to increase the method selectivity. Mobile phase was based on triethylamine buffer containing N,N-dimethyloctylamine as a modifier.

Early phase 2 inpatient rehabilitation after acute coronary syndrome treated with primary percutaneous coronary intervention: short- and long-term effects on blood pressure and metabolic parameters.

Objective: The aim of this study was to assess the 1-yr follow-up effects of inpatient rehabilitation and its prolongation with an ambulatory training program on blood pressure and metabolic risk factors in patients after an acute coronary syndrome.

Design: A controlled (n = 20) prospective study was undertaken. The study group consisted of 54 consecutive patients participating in a 3-wk inpatient rehabilitation.

Modification of a micellar system for amino acid separation by MEKC--application for amino acid profiling in formulations for parenteral use.

The paper proposes a new method for amino acid determination which can be applied for amino acid profiling in solutions for parenteral nutrition. The MEKC method based on a mixed micellar system was developed for the separation of 6-aminoquinolyl-N-hydroxysuccinimidyl carbamate (AQC) derivatized amino acids. Background electrolyte was based on tris-borate buffer with high alkaline pH.

Effects of Nordic walking training on exercise capacity and fitness in men participating in early, short-term inpatient cardiac rehabilitation after an acute coronary syndrome--a controlled trial.

Objective: To investigate the effects of Nordic Walking training supplemental to a standard, early rehabilitation programme on exercise capacity and physical fitness in men after an acute coronary syndrome.

Design: A controlled trial.

Setting: Cardiac rehabilitation service of a provincial hospital.

Capillary electrophoresis with indirect UV detection for the determination of stabilizers and citrates present in human albumin solutions.

Sodium caprylate and N-acetyltryptophan are the most frequently used stabilizers that protect the albumin from aggregation or heat induced denaturation. In turn citrates - excipients remaining after fractionation process - can be treated as by-product favoring leaching aluminum out of glass containers whilst albumin solution is stored. With ionic nature these substances have all the markings of a subject for capillary electrophoresis analysis.

Separation of synthetic food colourants in the mixed micellar system. Application to pharmaceutical analysis.

The paper presents a rapid method for the determination of commonly used synthetic food dyes by micellar electrokinetic capillary chromatography. Detection and separation conditions allowing complete resolution of 15 synthetic food colourants were investigated. The effect of different surfactants on the analytes mobility in relation to their structure was tested.

Application of a capillary electrophoresis method for simultaneous determination of preservatives in pharmaceutical formulations.

Preservatives are used to protect pharmaceutical formulations from microbial attack during the period of administration to the patient. Because of their biological activity, preservatives have to be identified and assayed according to the same rules as apply to active components. A number of methods for separation of preservatives are reported, to account for the heterogeneity of their chemical structures.

Short-term endurance training after coronary artery bypass grafting improves insulin resistance parameters in patients with hypertension.

Background: It has been shown that short-term exercise training improves insulin resistance parameters in patients with ischaemic heart disease. The effects of such a rehabilitation programme in patients with hypertension have not been well established.

Aim: To assess whether short-term endurance training after coronary artery bypass grafting (CABG) may improve metabolic parameters and reduce blood pressure in patients with hypertension.