One-Pot, Solvent Free Synthesis of 2,5-Furandicarboxylic Acid from Deep Eutectic Mixtures of Sugars as Mediated by Bifunctional Catalyst.

Currently one-pot conversion of sugars to 2,5-furandicarboxylic acid (FDCA) is of significant interest due to the attainability of sugars as a feedstock and the enormous potential of FDCA as a bioplastic monomer. However, it remains challenging to construct efficient catalysts for this process. In this study, CoO species were anchored to a sulfonated covalent organic framework thus affording a bifunctional catalyst (CoO@COF-SOH).

Ultrafine and well-dispersed Pd-Ni bimetallic catalyst stabilized by dendrimer-grafted magnetic graphene oxide for selective reduction of toxic nitroarenes under mild conditions.

A facile and efficient strategy is introduced for growing a dendrimer structure on the surface of magnetic graphene oxide by using thiol-ene click reaction. The as-synthesized dendrimer-grafted magnetic graphene oxide was used as a suitable support for bimetallic Pd-Ni nanoparticles. The prepared nanocomposite was utilized for the reduction of toxic nitroarenes to aminoarenes by using sodium borohydride in aqueous medium at room temperature.

Pd supported on clicked cellulose-modified magnetite-graphene oxide nanocomposite for C-C coupling reactions in deep eutectic solvent.

Cellulose-modified magnetite-graphene oxide nanocomposite was prepared via click reaction and utilized for immobilization of palladium (Pd) nanoparticles without using additional reducing agent. The abundant OH groups of cellulose provided the uniform dispersion and high stability of Pd nanoparticles, while magnetite-graphene oxide as a supporting material offered high specific surface area and easy magnetic separation. The as-prepared nanocomposite served as a heterogeneous catalyst for the Heck and Sonogashira coupling reactions in various hydrophilic and hydrophobic deep eutectic solvents (DESs) as sustainable and environmentally benign reaction media.

Effect of time interval between core preparation and post cementation on pushout bond strength of glass fiber-reinforced posts.

Introduction: The aim of this study was to investigate the effect of timing of coronal preparation on the pushout bond strength of fiber postluted with resin cement in the root canal.

Materials And Methods: In this experimental study, 48 mandibular human premolars were selected in a 3-week range. After root canal treatment and postspace preparation, a post #2(Angelus, Brazil) was cemented into the canal by a resin-based cement (Bifix SE, VOCO, Germany).