Enhanced pollutant photodegradation over nanoporous titanium-vanadium oxides with improved interfacial interactions.

This study addressed the separation problem of colloidal catalytic powder from its solution and pore blockage of traditional metallic oxides by fabricating nanoporous composites of titanium (Ti)-vanadium (V) oxide via magnetron sputtering, electrochemical anodization, and annealing processes. The effect of V-deposited loading on the composite semiconductors was investigated by varying V sputtering power (20-250 W) to correlate their physicochemical properties to the photodegradation performance of methylene blue. The obtained semiconductors revealed circular and elliptical pores (14-23 nm) and formed different metallic and metallic oxide crystalline phases.