The fate and mobility of chromium, arsenic and zinc in municipal sewage sludge during the co-pyrolysis process with organic and inorganic chlorides.

Co-pyrolysis is an efficient approach for municipal sewage sludge (SS) treatment, facilitating the production of biochar and promoting the stabilization and removal of heavy metals, particularly when combined with chlorinated materials. This study explores the impact of pyrolysis temperatures (400 °C and 600 °C) and chlorinated additives (polyvinyl chloride (PVC) as an organic chloride source and ferric chloride (FeCl) as an inorganic chloride source) at 10% and 20% concentrations, on the yield, chemical speciation, leachability, and ecological risks of arsenic (As), chromium (Cr), and zinc (Zn) in biochar derived from SS. The results revealed that increasing the pyrolysis temperature from 400 to 600 °C significantly reduced biochar yield due to enhanced volatilization of organic components, as well as the removal of heavy metals in interaction with chlorinated materials.

Effects of EDTA, citric acid, and tartaric acid application on growth, phytoremediation potential, and antioxidant response of L. in a cadmium-spiked calcareous soil.

The improved efficiency of cadmium (Cd) phytoextraction potential of L. was evaluated in Cd-spiked calcareous soil, using various chelating agents. In a greenhouse study, three chelating agents, including EDTA, citric acid (CA), and tartaric acid (TA), were applied to Cd-spiked soils (50 and 100 mg kg) under L.