This study utilized a facile one-pot protocol to synthesize Ni-cobalt zeolitic imidazolate framework (Ni-ZIF-67) nanocomposite, which was then characterized by Fourier transform infrared spectroscopy, X-ray diffraction, energy dispersive X-ray spectroscopy and scanning electron microscopy. The Ni-ZIF-67 nanocomposite was subsequently applied to modify a screen-printed electrode (SPE) as a durable sensor for detection of Sudan I concomitantly with bisphenol A (BPA), with remarkably increased electrochemical response when comparing with a bare SPE. The results showed the calibration plot to be linear in the concentration range between 0.
View Article and Find Full Text PDFMetal organic frameworks (MOF) are a class of hybrid networks of supramolecular solid materials comprising a large number of inorganic and organic linkers, all bound to metal ions in a well-organized fashion. Zeolitic imidazolate frameworks (ZIFs) are a sub-group of MOFs with imidazole as an organic linker to metals; it is rich in carbon, nitrogen, and transition metals. ZIFs combine the classical zeolite characteristics of thermal and chemical stability with pore-size tunability and the rich topological diversity of MOFs.
View Article and Find Full Text PDFIn this study, we prepared graphene oxide (GO)/ZIF-67 nanocomposites. Therefore, GO/ZIF-67 nanocomposites were used as a modifier on a screen-printed electrode (GO/ZIF-67/SPE) for studying the electrochemical behavior of epinine in phosphate buffer saline (PBS) at pH 7.0 with voltammetry techniques.
View Article and Find Full Text PDFA novel electrochemical sensing platform was designed and prepared for the simultaneous detection of sumatriptan and naproxen by exploiting the prowess of the FeO@ZIF-8 nanoparticles (NPs); as-synthesized FeO@ZIF-8 NPs were characterized by energy-dispersive X-ray spectroscopy, fourier transform infrared spectroscopy, X-ray diffraction, field emission scanning electron microscopy (FESEM), transmission electron microscopy and thermal gravimetric analysis. The immobilized FeO@ZIF-8 NPs on a screen printed graphite electrode (SPGE) was evaluated electrochemically via cyclic voltammetry, linear sweep voltammetry, and differential pulse voltammetry as well as chronoamprometery means; FeO@ZIF-8/SPGE exhibited good sensing performance for sumatriptan in a range of 0.035-475.
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