Photophysical properties of push-pull monocationic D-π-A thiophene based derivatives: Fluorosolvatochromism and pH studies.

Photophysical properties of two thiophene salts of the form D-π-A are studied in several solvents and at various pH values of the aqueous solution. The studied compounds embrace methoxy group as electron donating moiety at one end and cationic amidine group with and without fluorine atom at the ortho position of the amidine group as the electron withdrawing group at the other end of the molecules and separated by thiophene ring. The two thiophene derivatives are 4-(5-(4-methoxyphenyl)thiophen-2-yl)benzamidine hydrochloride salt (MOTB) and 2-fluoro-4-(5-(4-methoxyphenyl) thiophen-2-yl)benzamidine hydrochloride salt (FMOTB).