Publications by authors named "Magdalena Milek"

Article Synopsis
  • Thin films of an iron(ii) complex with a photochromic ligand were created and studied using various high-resolution spectroscopic techniques.
  • Research showed that the temperature-induced spin-crossover effect is maintained even at very low coverage (0.7 ML).
  • However, the expected photo-switching of the spin state is not seen in sub-monolayer films due to interactions between the ligand and the substrate that stabilize the inactive form of the ligand.
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Spin-crossover metal complexes are highly promising magnetic molecular switches for prospective molecule-based devices. The spin-crossover molecular photoswitches developed so far operate either at very low temperatures or in the liquid phase, which hinders practical applications. Herein, we present a molecular spin-crossover iron(II) complex that can be switched between paramagnetic high-spin and diamagnetic low-spin states with light at room temperature in the solid state.

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During the past 10 years iron-catalyzed reactions have become established in the field of organic synthesis. For example, the complex anion [Fe(CO)3 (NO)](-) , which was originally described by Hogsed and Hieber, shows catalytic activity in various organic reactions. This anion is commonly regarded as being isoelectronic with [Fe(CO)4 ](2-) , which, however, shows poor catalytic activity.

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A photoisomerizable diarylethene-derived ligand, phen*, has been successfully introduced into a spin-crossover iron(II) complex, [Fe(H2B(pz)2)2phen*] (1; pz =1-pyrazolyl). A ligand-based photocyclization (photocycloreversion) in 1 modifies the ligand field, which, in turn, results in a highly efficient paramagnetic high-spin → diamagnetic low-spin (low-spin → high-spin) transition at the coordinated Fe(II) ion. The reversible photoswitching of the spin states, and thus the associated magnetic properties, has been performed in solution at room temperature and has been directly monitored by measuring the magnetic susceptibility via the Evans method.

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A bisoxamate ligand containing three different types of coordination sites was designed and synthesized. The developed synthetic strategy was adopted to prepare a related 1,2-bis(2-hydroxybenzamido)benzene-derived ligand. Nickel(II) complexes of both the novel ligands were obtained and characterized by X-ray crystallography, NMR, electronic absorption spectroscopy, and theoretical calculations.

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