Pickering Emulsions: Role of Particle Wettability and Adhesive Force on Droplet Bridging.

This study demonstrates the engineering of bridged Pickering emulsion (PE) gels by tuning the particle position at the interface and adhesive forces. This is achieved through controlled surface modification of hematite particles using oleic acid in a water-decane system. Microscopy observations revealed that the droplets are stabilized through a bridging mechanism, where oil droplets are connected by a shared monolayer of particles, with an intervening water layer between them.

Polymer-Mediated Crack Suppression in Deposit of Nanoellipsoids.

Uniform distribution of particles and crack suppression in dried particulate deposits are major challenges for applications in coating and printing technologies. To address this, we investigated the impact of the addition of a water-soluble polymer, poly(vinyl alcohol) (PVA), on the evaporative self-assembly and kinetics of crack formation in deposits of anisotropic colloids. The fluid flow inside the drying drop is significantly altered due to polymer-mediated adsorption of ellipsoids to the drop surface.

Investigating the optical and electrical performance of rod coated silver nanowire-based transparent conducting films.

Silver nanowires (Ag NWs) are highly promising building blocks for developing transparent conducting films (TCFs) due to their high electrical conductivity and good optical transparency. The large-scale production of Ag NW-based high-quality TCFs using low-cost processing methods can replace the traditional oxide based TCFs. Therefore, developing a reliable technique for large-scale fabrication of Ag NW-based TCFs is vital.

Association in Like-Charged Surfactant-Nanoparticle Systems: Interfacial and Bulk Effects.

The association of similarly charged surfactant molecules and nanoparticles in an aqueous solution remains unresolved, and the understandings reported in the literature are conflicting. To address this issue, we undertake a fundamental study to investigate bulk and interfacial phenomena in binary mixtures of (i) positively charged nanoparticles and cationic surfactants and (ii) negatively charged nanoparticles and anionic surfactants. We find that the surfactant molecules adsorb on the surface of the nanoparticle despite similar charge, leading to supercharging of particles and simultaneously driving more surfactant molecules to the air-dispersion interface.

Soft colloidal monolayers with reflection symmetry through confined drying.

Colloidal monolayers serve as fundamental building blocks in fabricating diverse functional materials, pivotal for surface modifications, chemical reactivity, and controlled assembly of nanoparticles. In this article, we report the formation of colloidal monolayers generated by drying an aqueous droplet containing soft colloids confined between two hydrophilic parallel plates. The analysis of the kinetics of evaporation in this confined mode showed that: (i) for a significant portion of the drying time, the drops adopt a catenoid configuration; (ii) in the penultimate stage of drying, the catenoid structure undergoes division into two daughter droplets; (iii) the three-phase contact line remains pinned at a specific location while it continuously slips at all other locations.

Drying-Induced Flash Nanoprecipitation in a Sessile Drop: A Route to Synthesize Polymeric Nanoparticles.

Flash nanoprecipitation is a simple and scalable method to produce nanoparticles by rapid mixing of a polymer solution with an antisolvent. High-speed mixing devices for the continuous synthesis of polymeric nanoparticles and drug-encapsulated nanoparticles have been designed. In this work, we demonstrate a different approach to induce flash nanoprecipitation using the differential evaporation of solvents in a sessile drop.

Demulsification of Pickering Emulsions by Chemical Dissolution of Stabilizers.

Demulsification of particle-stabilized oil-in-water emulsions is crucial in diverse fields such as treatment of produce water, recovery of valuable products of Pickering emulsion catalysis, and so on. In this work, we investigated a facile method for destabilizing emulsions by dissolving stabilizer particles by the introduction of acid or base. Nanoellipsoidal hematite-stabilized decane-in-water emulsions are destabilized by dissolving hematite with oxalic or hydrochloric acid in situ.

Quantifying the Microstructure of Dried Deposits Using Height-Height Correlation Function.

Colloidal self-assembly has garnered significant attention in recent research, owing to applications in medical and engineering domains. Understanding the arrangement of particles in self-assembled systems is crucial for comprehending the underlying physics and synthesizing complex nano- and microscale structures. In this study, we introduce a novel methodology for analyzing the spatial distribution of particles in colloidal assemblies, focusing specifically on quantifying the microstructure of deposits formed by the evaporation of colloidal particle-laden drops.

Single-Step Formation of Pickering Double Emulsions by Exploiting Differential Wettability of Particles.

We present a modular single-step strategy for the formation of single and Pickering double emulsions (DEs). To this end, we consider the role of surface modification of particles and their dispersibility in different phases in the context of the design of Pickering emulsions by varying the volume fraction of oil in the oil-water mixture (ϕ) used for emulsification. In particular, the experiments are performed by considering (a) model spherical and nonspherical colloids of different wettabilities which are tailored by oleic acid treatment, (b) immiscible liquids with or without particles, and (c) varying ϕ from 0.

Morphologies of electric-field-driven cracks in dried dispersions of ellipsoids.

We report an experimental and theoretical study of the morphology of desiccation cracks formed in deposits of hematite ellipsoids dried in an externally applied alternating current (ac) electric field. A series of transitions in the crack morphology is observed by modulating the frequency and the strength of the applied field. We also found a clear transition in the morphology of cracks as a function of the aspect ratio of the ellipsoid.

Dynamics of spreading of an asymmetrically placed droplet near a fluid-fluid interface.

Two-dimensional numerical simulations are carried out to study the spreading dynamics of a droplet placed in the vicinity of a fluid-fluid interface. Simulations are performed using the hybrid lattice-Boltzmann technique and the diffuse-interface model by considering three immiscible fluids of the same density and viscosity. In contrast to the well-studied spreading of drops placed symmetrically across fluid-fluid interfaces, this work considers the simultaneous migration, spreading and eventual adsorption of an asymmetrically placed drop.

Emulsions as Viable Alternative to Conventional Fuels: Current Status and Challenges.

The scientific investigation of water-in-fuel emulsions spans over five decades; however, the widespread implementation of emulsion fuels in commercial settings has proven to be a challenging endeavor. This Perspective discusses the current status of the research pertaining to the formation and stability of emulsion fuels, technical and regulatory challenges, and opportunities. In particular, we highlight the need for a coordinated effort between the colloid and interface community and those actively investigating emissions, spray characteristics, and combustion aspects in internal combustion engines.

Conducting Gold Nanoparticle Films via Sessile Drop Evaporation.

The deposit patterns obtained from the evaporation of drops containing insoluble solute particles are vital for several technologies, including inkjet printing and optical and electronic device manufacturing. In this work, we consider the evaporation of an aqueous reaction mixture typically used for gold nanoparticle (AuNP) synthesis. The patterns obtained from the evaporation-driven assembly of in situ generated AuNPs are studied using optical microscopy and SEM analyses.

Design of spinning disk atomization equipment for synthesis of drug-loaded microparticles.

The synthesis of drug-loaded microparticles with precise control over size distribution and shape is crucial for achieving desired drug distribution in microparticles and tuning drug release profiles. Common large-scale production techniques produce microparticles with a broad particle size distribution and require challenging operating conditions. Recent methods employing microfluidics have enabled the production of microparticles with a uniform size distribution.

Oil-in-Water Emulsions Stabilized by Hydrophilic Homopolymers.

Most of the polymeric emulsifiers have diblock and triblock copolymer architecture containing hydrophilic and hydrophobic domains. In this work, we show that hydrophilic homopolymers can be effective stabilizers of oil-in-water emulsions. Using polyethelyne oxide and poly(vinylpyrrolidone) as model hydrophilic homopolymers and n-decane and n-hexane as model nonpolar phases, we show that high-molecular weight polymers can stabilize emulsions over 24 h beyond a threshold concentration.

Modulating shape transition in surfactant stabilized reverse microemulsions.

The formation of reverse microemulsions (RMs) of spherical shape in the oil/water/surfactant ternary mixture at high molar ratio of water to surfactant () is well established. Using dynamic light scattering, small-angle X-ray and neutron scattering, we elucidate the formation of non-spherical reverse microemulsions stabilised by sodium bis(2-ethylhexyl) sulfosuccinate (AOT) at = 10 and volume fractions of the dispersed phase, , ranging from 0.005 to 0.

Effect of Colloidal Surface Charge on Desiccation Cracks.

We report the effect of polarity and surface charge density on the nucleation and growth kinetics of desiccation cracks in deposits of colloids formed by drying. We show that the average spacing between desiccation cracks and crack opening are higher for the deposit of positively charged colloids than that of negatively charged colloids. The temporal evolution of crack growth is found to be faster for positively charged particle deposits.

Kinetics of evaporation of colloidal dispersion drops on inclined surfaces.

Evaporation of colloidal dispersion drops leaves a deposit pattern where more particles are accumulated at the edge, popularly known as the coffee-ring effect. Such patterns formed from dried sessile drops are azimuthally symmetric. When the substrate is inclined, the symmetry of the patterns is altered due to the influence of gravity.

Investigation of Nanostructure and Interactions in Water-in-Xylene Microemulsions Using Small-Angle X-ray and Neutron Scattering.

The ability to modulate the size, the nanostructure, and the macroscopic properties of water-in-oil microemulsions is useful for a variety of technological scenarios. To date, diverse structures of water-in-alkane microemulsions stabilized by sodium bis(2-ethylhexyl) sulfosuccinate (AOT) have been extensively studied. Even though the decisive parameter which dictates the phase behavior of micremulsions is the nature of the continuous phase, relatively very few reports are available on the structure and interactions in the microemulsions of aromatic oil.

Drying Drops of Colloidal Dispersions.

Drying drops of colloidal dispersions have attracted attention from researchers since the nineteenth century. The multiscale nature of the problem involving physics at different scales, namely colloidal and interfacial phenomena as well as heat, mass, and momentum transport processes, combined with the seemingly simple yet nontrivial shape of the drops makes drying drop problems rich and interesting. The scope of such studies widens as the physical and chemical nature of dispersed entities in the drop vary and as evaporation occurs in more complex configurations.

Electrostatic Heteroaggregation: Fundamentals and Applications in Interfacial Engineering.

The aggregation of oppositely charged soft materials (particles, surfactants, polyelectrolytes, etc.) that differ in one or more physical or chemical attributes, broadly referred to as electrostatic heteroaggregation, has been an active area of research for several decades now. While electrostatic heteroaggregation (EHA) is relevant to diverse fields such as environmental engineering, food technology, and pharmaceutical formulations, more recently there has been a resurgence to explore various aspects of this phenomenon in the context of interface stabilization and the development of functional materials.

Tailoring Pickering Double Emulsions by in Situ Particle Surface Modification.

Fundamental studies on the formation and stability of Pickering double emulsions are crucial for their industrial applications. Available methods of double emulsion preparation involve multiple tedious steps and can formulate a particular type of double emulsion, that is, water-in-oil-in-water (w/o/w) or oil-in-water-in-oil (o/w/o). In this work, we proposed a simple single-step in situ surface modification method to stabilize different types of double emulsions using hematite and silica particle systems which involves the addition of oleic acid.

Storage and Temperature Stability of Emulsified Biodiesel-Diesel Blends.

The scarcity of fossil fuel has led to the recent worldwide commercialization of biodiesel-blended diesel. The benefits associated with emulsion fuels have encouraged researchers to study the blended emulsified fuels in diesel engines. Recent results show the effectiveness of blended emulsified fuels in terms of better fuel economy and less harmful emissions.

Destabilization of Pickering emulsions by interfacial transport of mutually soluble solute.

Hypothesis: Pickering emulsions (PEs) once formed are highly stable because of very high desorption energies (∼10 kT) associated with particles adsorbed to the interfaces. The destabilization of PEs is required in many instances for recovery of valuable chemicals, products and active compounds. We propose to exploit interfacial instabilities develop by the addition of different types of solutes to PEs as a route to engineer their destabilization.

Plant Latex as a Versatile and Sustainable Emulsifier.

Emulsions are a class of high-surface-energy materials typically stabilized by surfactants, polymers, particles, or a combination of these. There has been considerable effort to develop new emulsifiers by exploiting developments in synthetic chemistry; however, synthetic surface-active species may assist in the stabilization of a specific type of immiscible liquid-liquid systems. That is, one stabilizer does not provide a solution for all interface stabilization problems.