Publications by authors named "Madhuprasad Kigga"

A rhodamine-derived receptor was synthesized and comprehensively characterized for structural confirmation. The receptor was able to distinguish the copper ions (Cu) from other competing cations. The yellow color of the receptor changed to pink upon adding Cu ions, however, other competing cations ions were impotent towards any color variation.

View Article and Find Full Text PDF

This study presents a novel approach to decontaminate ferrocyanide-contaminated wastewater. The work effectively demonstrates the use of bimetallic Mo/Zr-UiO-66 as a super-adsorbent for rapid sequestration of Prussian blue, a frequently found iron complex in cyanide-contaminated soils/groundwater. The exceptional performance of Mo/Zr-UiO-66 is attributed to the insertion of secondary metallic sites, which deliver synergistic effects, benefiting the inherent qualities of the framework.

View Article and Find Full Text PDF

A Schiff base receptor with an active -NH group was designed and synthesized for the selective and sensitive colorimetric detection of inorganic fluoride (F) ions in an aqueous medium. The sensitivity of the receptor for F ions was enhanced by the influence of two electron-withdrawing -NO groups at ortho and para positions which result in a vivid color change. The receptor underwent a remarkable color change from light yellow to violet, enabling naked-eye detection of F ions without the need for spectroscopic equipment.

View Article and Find Full Text PDF

In this study, hydrophilic activated carbon has been prepared and used to synthesize innovative activated carbon/polysulfone mixed matrix membranes (MMMs). These membranes were investigated in terms of membrane morphology, hydrophilicity, antifouling ability, and metal ions rejection. The activated carbon (AC) was prepared from a simple chemical activation method using Rhizophora mucronata propagules, which are rich in aerenchyma cells and possess a high surface area.

View Article and Find Full Text PDF

Metal-organic frameworks (MOFs) are a versatile class of porous materials offering unprecedented scope for chemical and structural tunability. On account of their synthetic versatility, tunable and exceptional host-guest chemistry they are widely utilized in many prominent water remediation techniques. However, some of the MOFs present low structural stabilities specifically in aqueous and harsh chemical conditions which impedes their potential application in the field.

View Article and Find Full Text PDF

CTCs (circulating tumor cells) are well-known for their use in clinical trials for tumor diagnosis. Capturing and isolating these CTCs from whole blood samples has enormous benefits in cancer diagnosis and treatment. In general, various approaches are being used to separate malignant cells, including immunomagnets, macroscale filters, centrifuges, dielectrophoresis, and immunological approaches.

View Article and Find Full Text PDF

Herein, we demonstrate the use of cerium (Ce)-UiO-66 metal organic framework (MOF) for the removal of a variety of potentially toxic pollutants. The Ce-UiO-66 MOF, with similar framework topologies to Zr-UiO-66, has not been explored for its adsorptive properties in water remediation. The replacement of Zr metal center with Ce yields a MOF that can be synthesized in shorter durations with lesser energy consumptions and with excellent multipollutant adsorption properties.

View Article and Find Full Text PDF

A PDMS (Polydimethylsiloxane) microfluidic channel coupled with UV-vis fibre-optic spectrometer and new synthesized colorimetric probe was integrated into an optofluidic based Lab-on-a-chip device for highly sensitive and real-time quantitative measurements of fluoride ions (F¯). An 'S' shaped microchannel in a microfluidic device was designed to act as microreactor to facilitate the continuous reaction between synthetized colorimetric probe (sensor) and F¯ ions. Following this reaction, the UV-vis optical probe in the downstream detection zone of the microfluidic device was used to capture their spectrum and present as F¯ concentration in real-time conditions.

View Article and Find Full Text PDF

The significant upsurge in the demand for freshwater has prompted various developments towards water sustainability. In this context, several materials have gained remarkable interest for the removal of emerging contaminants from various freshwater sources. Among the currently investigated materials for water treatment, metal organic frameworks (MOFs), a developing class of porous materials, have provided excellent platforms for the separation of several pollutants from water.

View Article and Find Full Text PDF
Article Synopsis
  • Toxic pollutants like dyes and metal ions in water can harm the environment, so it's important to find ways to remove them.
  • Diatomaceous earth (DE) is a cheap and effective tool for cleaning water, especially when it's specially modified.
  • This review looks at how well surface-modified DE can remove these pollutants, its different modification methods, and compares their costs and effectiveness.
View Article and Find Full Text PDF

The polluted water sources pose a serious issue concerning the various health hazards they bring along. Due to various uncontrolled anthropogenic and industrial activities, a great number of pollutants have gained entry into the water systems. Among all the emerging contaminants, anionic species such as fluoride cause a major role in polluting the water bodies because of its high reactivity with other elements.

View Article and Find Full Text PDF

Diatomaceous earth or diatom (DE) are naturally available and low cost micro particles with distinct porous structure were used as an adsorbent for the removal of a hazardous dye, Eriochrome Black T (EBT). The surface modification of these DE were performed by sol-gel and hydrothermal methods to obtain a series of adsorbents such as diatom-ceria (DC), diatom-silica xerogel (DX), and diatom-silica xerogel-ceria (DXC). A cauliflower like morphology structure of ceria was observed on DE and DX.

View Article and Find Full Text PDF

A PHP Error was encountered

Severity: Notice

Message: fwrite(): Write of 34 bytes failed with errno=28 No space left on device

Filename: drivers/Session_files_driver.php

Line Number: 272

Backtrace:

A PHP Error was encountered

Severity: Warning

Message: session_write_close(): Failed to write session data using user defined save handler. (session.save_path: /var/lib/php/sessions)

Filename: Unknown

Line Number: 0

Backtrace: