Triazole-rich 3D metal-organic framework incorporated solid electrolytes for superior proton conductivity and durability in fuel cells.

Insufficient proton conductivity and oxidative stability of sulfonated hydrocarbons hinder their applicability as proton exchange membrane electrolytes in fuel cells. In this regard, fabrication of proton conducting mixed-matrix membranes (PC-MMMs) can be a superior approach to obtain desirable properties. In this work, a triazole ligand (1H-1,2,4 triazole) was coordinated to a zinc metal node to create a 3D metal-organic framework (MOF) and incorporated as an additive in a sulfonated poly(ether ether ketone) matrix at 1, 3, and 5 weight percentage to fabricate PC-MMMs by the casting process.