Parts-Per-Million Carbonate Mineral Quantification with Thermogravimetric Analysis-Mass Spectrometry.

Mitigating the deleterious effects of climate change requires the development and implementation of carbon capture and storage technologies. To expand the monitoring, verification, and reporting (MRV) capabilities of geologic carbon mineralization projects, we developed a thermogravimetric analysis-mass spectrometry (TGA-MS) methodology to enable quantification of <100 ppm calcite (CaCO) in complex samples. We extended TGA-MS calcite calibration curves to enable a higher measurement resolution and lower limits of quantification for evolved CO from a calcite-corundum mixture.