Photocatalysts of TiO-CuO coupled with 30% graphene oxide (GO) were hydrothermally fabricated, which varied the TiO to CuO weight ratios to 1:4, 1:2, 1:1, 2:1 and 4:1 and reduced to form TiO-CuO/reduced graphene oxide (rGO) photocatalysts. They were characterized using XRD, TEM, SEM, XPS, Raman, and DRS technologies. TiO-CuO composites and TiO-CuO/GO degrade methylene blue when persulfate ions are present.
View Article and Find Full Text PDFPolyethyleneglycol-coated biocompatible CuO-ZnO nanocomposites were fabricated hydrothermally varying Zn:Cu ratios as 1:1, 2:1, and 1:2, and their antibacterial activity was determined through the well diffusion method against the Gram-negative Escherichia coli, Pseudomonas aeruginosa, Klebsiella pneumoniae, and the Gram-positive Staphylococcus aureus. The minimum inhibitory concentration and the minimum bactericidal concentration values of the synthesized samples were determined. Subsequently, the time synergy kill assay was performed to elucidate the nature of the overall inhibitory effect against the aforementioned bacterial species.
View Article and Find Full Text PDFFabrication of chitosan and ilmenite sand-based novel photocatalysts through the catalytic graphitization of chitosan is reported. Nanocomposites consisted of TiO, FeO and Fe nanoparticles dispersed on a nitrogen-doped graphitic carbon framework. The surface area, pore volume and macropore structure of the carbon matrix is disturbed by the heterogeneously distributed nanoparticles.
View Article and Find Full Text PDFChitosan derived from chitin gas gathered much interest as a biopolymer due to its known and possible broad applications. Chitin is a nitrogen-enriched polymer abundantly present in the exoskeletons of arthropods, cell walls of fungi, green algae, and microorganisms, radulae and beaks of molluscs and cephalopods, etc. Chitosan is a promising candidate for a wide variety of applications due to its macromolecular structure and its unique biological and physiological properties, including solubility, biocompatibility, biodegradability, and reactivity.
View Article and Find Full Text PDFHematite (α-FeO) and pseudobrookite (FeTiO) suffer from poor charge transport and a high recombination effect under visible light irradiation. This study investigates the design and production of a 2D graphene-like r-GO/GO coupled α-FeO/FeTiO heterojunction composite with better charge separation. It uses a simple sonochemical and hydrothermal approach followed by L-ascorbic acid chemical reduction pathway.
View Article and Find Full Text PDFACS Omega
July 2022
Dyes in wastewater are a serious problem that needs to be resolved. Adsorption coupled photocatalysis is an innovative technique used to remove dyes from contaminated water. Novel composites of TiO-FeC-Fe-FeO dispersed on graphitic carbon were fabricated using natural ilmenite sand as the source of iron and titanium, and sucrose as the carbon source, which were available at no cost.
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