Exceptional behavior of light-matter interaction in the extreme ultraviolet is demonstrated. The photoionization of different rare gases was compared at the free-electron laser in Hamburg, FLASH, by applying ion spectroscopy at the wavelength of 13.7 nm and irradiance levels of thousands of terawatts per square centimeter.
View Article and Find Full Text PDFThe Xe 5s nondipole photoelectron parameter gamma is obtained experimentally and theoretically from threshold to approximately 200 eV photon energy. Significant nondipole effects are seen even in the threshold region of this valence shell photoionization. In addition, contrary to previous understanding, clear evidence of interchannel coupling among quadrupole photoionization channels is found.
View Article and Find Full Text PDFA new and explicitly many-body aspect of the "leveraging" of the spin-orbit interaction is demonstrated, spin-orbit activated interchannel coupling, which can significantly alter the photoionization cross section of a spin-orbit doublet. As an example, it is demonstrated via a modified version of the spin-polarized random phase approximation with exchange, that a recently observed unexplained structure in the Xe 3d(5/2) photoionization cross section [A. Kivimäki et al.
View Article and Find Full Text PDFIt is demonstrated that the nonrelativistic high energy omega-->infinity behavior of the photoionization cross section of an nl atomic subshell, sigma(nl)(omega), for l>0 is independent of l and is given by sigma(nl)(omega) approximately 1/omega(9/2), rather than the previously generally accepted sigma(nl)(omega) approximately 1/omega(l+7/2). Furthermore, for l = 1, although the exponent does not change, the coefficient is significantly altered. This modification of sigma(nl)(omega) is due to the interchannel interaction between ns photoionization channels and l not equal0 channels in the atom.
View Article and Find Full Text PDFThe recent developments and the physical backgrounds of the random phase approximation with exchange (RPAE) method are briefly discussed. The limitations of RPAE and the main features of a more general theory that would be free of RPAE difficulties are considered. The generalizations of RPAE are discussed that permit one to take into account the rearrangement of electron shells in the course of ionization and the effects due to the decay of the vacancy created in the ionization process.
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