Publications by authors named "M Zavelani-Rossi"

One-dimensional (1D) linear nanostructures comprising -hybridized carbon atoms, as derivatives of the prototypical allotrope known as carbyne, are predicted to possess outstanding mechanical, thermal, and electronic properties. Despite recent advances in their synthesis, their chemical and physical properties are still poorly understood. Here, we investigate the photophysics of a prototypical polyyne (i.

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The interest in compact, cost-effective, and versatile accelerators is increasing for many applications of great societal relevance, ranging from nuclear medicine to agriculture, pollution control, and cultural heritage conservation. For instance, Particle Induced X-ray Emission (PIXE) is a non-destructive material characterization technique applied to environmental analysis that requires MeV-energy ions. In this context, superintense laser-driven ion sources represent a promising alternative to conventional accelerators.

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  • The study explores the optoelectronic properties of 3-hydroxyflavone (3HF) when self-assembled on n-type semiconductors (like TiO) and insulators (like AlO).
  • 3HF forms metal complexes using unsaturated metal ions on oxide surfaces, affecting their light behavior based on the metal ion involved.
  • The findings indicate that the photoluminescence can be adjusted through the metal ion, achieving solid-state emitters with a quantum yield of about 15% and allowing control over photoinduced charge injection.
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  • * The study introduces a model system with sulfur vacancies in CdSeS NCs, creating a donor state that leads to long-lived intragap luminescence and improved emission efficiency up to 85%.
  • * Magneto-optical measurements reveal that the localized electrons are unaffected by the NC bands, with the photohole spin dynamics slowed due to reduced exchange interactions.
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"Charge engineering" of semiconductor nanocrystals (NCs) through so-called electronic impurity doping is a long-standing challenge in colloidal chemistry and holds promise for ground-breaking advancements in many optoelectronic, photonic, and spin-based nanotechnologies. To date, our knowledge is limited to a few paradigmatic studies on a small number of model compounds and doping conditions, with important electronic dopants still unexplored in nanoscale systems. Equally importantly, fine-tuning of charge engineered NCs is hampered by the statistical limitations of traditional approaches.

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