Linear conjugated molecules consisting of benzothiadiazole (BTD) and phenyl rings are highly efficient organic luminophores. Crystals based on these compounds have great potential for use as light-emitting elements, in particular, scintillation detectors. This paper compares the peculiarities of growth, structure, and fluorescent properties of crystals based on 4,7-diphenyl-2,1,3-benzothiadiazole () and its organosilicon derivative 4,7-bis(4-(trimethylsilyl)phenyl) BTD ().
View Article and Find Full Text PDFActa Crystallogr B Struct Sci Cryst Eng Mater
April 2022
A new linear luminophore consisting of five conjugated units of oxazole, phenylene and a central benzothiadiazole fragment, 4,7-bis[4-(1,3-oxazol-5-yl)phenyl]-2,1,3-benzothiadiazole, has been synthesized and characterized. Needle-like single-crystal samples up to 10 mm in length were obtained by physical vapor transport. The crystal structure was determined at 95 K and 293 K using single-crystal X-ray diffraction.
View Article and Find Full Text PDFAn obesity is the topical problem worldwide, because excessive weight is the reason of metabolic changes that lead to development of serious chronic non-communicable diseases. The examination was aimed to assess clinical and metabolic health, nutritional status and behavior risk factors of obesity in people, working at the industrial plant. .
View Article and Find Full Text PDFActa Crystallogr B Struct Sci Cryst Eng Mater
December 2019
The synthesis, growth from solutions and structure of crystals of a new linear thiophene-phenylene co-oligomer with a central benzothiadiazole fragment with a conjugated core, (TMS-2T-Ph)-BTD, are presented. Single-crystal samples in the form of needles with a length of up to 7 mm were grown and their crystal structure was determined at 85 K and 293 K using single-crystal X-ray diffraction. The conformational differences between the crystal structures are insignificant.
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