Electrocatalytic CO Reduction to Methanol on Pt(111) Modified with a Pd Monolayer.

Electrochemical carbon dioxide (CO) conversion to value-added, highly reduced chemicals such as methanol (CHOH) is a promising possibility for producing renewable fuel and simultaneous CO recycling. However, this process remains a challenge, with only a few selective electrocatalysts known. Here, we present a study of a palladium monolayer on a platinum (111) single crystal (Pd/Pt(111)) as an electrocatalyst for CO conversion to CHOH.

Platinum hydride formation during cathodic corrosion in aqueous solutions.

Cathodic corrosion is an electrochemical phenomenon that etches metals at moderately negative potentials. Although cathodic corrosion probably occurs by forming a metal-containing anion, such intermediate species have not yet been observed. Here, aiming to resolve this long-standing debate, our work provides such evidence through X-ray absorption spectroscopy.

Electrolyte Effects on Electrochemical CO Reduction Reaction at Sn Metallic Electrode.

Understanding the electrolyte factors governing the electrochemical CO reduction reaction (CORR) is fundamental for selecting the optimized electrolyte conditions for practical applications. While noble metals are frequently studied, the electrolyte effects on the CORR on Sn catalysts are not well explored. Here, we studied the electrolyte effect on Sn metallic electrodes, investigating the impact of electrolyte concentration, cation identity, and anion properties, and how it shapes the CORR activity and selectivity.

Microbiome-Derived Trimethylamine N-Oxide (TMAO) as a Multifaceted Biomarker in Cardiovascular Disease: Challenges and Opportunities.

Biomarkers play a crucial role in various stages of disease management, including screening, diagnosis, prediction, prognosis, treatment, and safety monitoring. Although they are powerful tools in disease diagnosis, management, and drug development, identifying and validating reliable biomarkers remains a significant challenge. Among potential microbiome-derived biomarkers, trimethylamine N-oxide (TMAO) has gained notable attention for its link to atherosclerosis and cardiovascular risk.