Natural (OP) and iron modified orange peel (Fe-OP) were used for the removal of tetracycline from aqueous solutions in batch and fixed bed column systems. The adsorbents were characterized by infrared spectroscopy (IR) and the morphologies of the surfaces before and after tetracycline removal were determined by scanning electron microscope and the elemental analysis was performed by X-ray dispersive spectroscopy (EDS). The kinetic behaviour showed that the equilibrium was reached in 24 and 10 h for OP and Fe-OP respectively, the data were adjusted to both the pseudo second order and intraparticle diffusion models which indicate a chemisorption mechanism and the adsorption process is controlled by the intraparticle diffusion process.
View Article and Find Full Text PDFJ Environ Sci Health A Tox Hazard Subst Environ Eng
July 2022
The adsorption of praseodymium using hydroxyapatite was evaluated. The hydroxyapatite (HAP) was characterized by X-ray diffraction (JCPDS 01-04-3708), scanning electron microscopy, BET specific surface area (54.2 m/g), and point of zero charge (6.
View Article and Find Full Text PDFRadionuclides in the environment is an important issue, many techniques have been developed for the removal of radionuclides from the environment. One of those techniques is the adsorption and natural and synthesized materials have been used to remove different radionuclides from water. The adsorbents used for removal of radionuclides should have high retention capacity and they should be resistant to radiation.
View Article and Find Full Text PDFThe behaviour of cerium, as a prototype of the lanthanide group, against the inorganic components of two types of soils (one from an forest (IM-F) and the other from a semiarid zone (IM-S)) was investigated. The pseudo-second order model applied to the kinetics adsorption data for both soils indicated chemical adsorption; the equilibrium was reached in less than 4 h, the adsorption of Ce(III) in these conditions were 15.6 and 3.
View Article and Find Full Text PDFJ Environ Sci Health A Tox Hazard Subst Environ Eng
June 2019
The physicochemical treatment (PT) of slaughterhouse wastewater (SWW) was investigated. In the first stage, calcium acetate (Ca(Ac)) was synthesized in five different ways: (1) acetic acid (HAc) and chicken eggshell (CaAc1), (2) lime (CaAc2), (3) a 1:1 eggshell and lime mixture (CaAc3), (4) a 1:2 eggshell and lime mixture (CaAc4), and (5) calcium oxide via the calcination of eggshell (CaAc5). The synthesized Ca(Ac) samples were characterized by IR, SEM, XRD, and EDS.
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