Genome sequencing and characterization of microsatellite markers of L.f.: an economically important endangered tree of Eastern Ghats, India.

L.f. (red sanders) is an endemic, endangered and economically important tree species distributed in the Eastern Ghats of Andhra Pradesh, India.

Photoredox-HAT Catalysis for Primary Amine α-C-H Alkylation: Mechanistic Insight with Transient Absorption Spectroscopy.

The synergistic use of (organo)photoredox catalysts with hydrogen-atom transfer (HAT) cocatalysts has emerged as a powerful strategy for innate C(sp)-H bond functionalization, particularly for C-H bonds α- to nitrogen. Azide ion (N) was recently identified as an effective HAT catalyst for the challenging α-C-H alkylation of unprotected, primary alkylamines, in combination with dicyanoarene photocatalysts such as 1,2,3,5-tetrakis(carbazol-9-yl)-4,6-dicyanobenzene (4CzIPN). Here, time-resolved transient absorption spectroscopy over sub-picosecond to microsecond timescales provides kinetic and mechanistic details of the photoredox catalytic cycle in acetonitrile solution.

Multifarious extraction methodologies for ameliorating lipid recovery from algae.

Amongst the current alternatives, algae were proven to be a promising source of biofuel, which is renewable and capable of meeting world demand for transportation fuels. However, a suitable lipid extraction method that efficiently releases the lipids from different algal strains remains a bottleneck. The multifarious pretreatment methods are prevalent in this field of lipid extraction, and therefore, this article has critically reviewed the various lipid extraction methods for ameliorating the lipid yield from algae, irrespective of the strains/species.

Particulate matter exposure analysis in 12 critical urban zones of Chennai, India.

This research paper examines the exposure to particulate matter (PM) and its deposition on the human respiratory tract (HRT) in 12 critical urban zones - institutional zone, commercial zone, construction zone, hospital zone, landfill zone, industrial zone, residential zone, high-traffic zone, main roads, medium-traffic zone secondary roads, low-traffic zone, coastal zone, and environmentally sensitive zone. This study measured the size-segregated PM concentrations using a Grimm aerosol spectrometer. The multiple-path particle dosimetry model assesses particles' total and regional deposition mass rates for different urban zones.