Here we report on the occurrence of mycosporine-like amino acids (MAAs) in the Argentine shortfin squid, Illex argentinus, the second fishery resource mostly exploited in the Argentinean continental shelf. The total content of four MAAs was evaluated by reverse-phase-HPLC in different tissues (eyes, skin, liver, and gonads). Also, the antioxidant activity of crude extracts was assessed by in-vitro determinations: 2,2'-azino-bis(3-ethylbenzothiazoline-6-sulfonic acid) (ABTS), 2,2-diphenyl-1-picrylhydrazyl (DPPH), Folin-Ciocalteu, and ferrous ion-chelating capacity assays.
View Article and Find Full Text PDFHere, we present the synthesis of a highly efficient V-doped α-AgWO catalyst for the oxidation of sulfides to sulfones, exhibiting a high degree of tolerance towards various sensitive functional groups. Remarkably, the catalysts with 0.01% V-doping content exhibited outstanding selectivity towards the oxidation process.
View Article and Find Full Text PDFHeavy metal pollution is becoming a worldwide problem affecting pollinators. The massive use of lead (Pb), the most harmful metal for the biosphere, in industries has increased the risk for honey bees. Pb exerts toxicity on living organisms inducing mainly oxidative stress.
View Article and Find Full Text PDFComp Biochem Physiol B Biochem Mol Biol
January 2024
Paenibacillus larvae, the causal agent of American foulbrood disease (AFB), affects Apis mellifera larvae and can induce oxidative stress by overproduction of radical oxygen species (ROS). This study aimed to assess the oxidative stress levels in larvae exposed to three different strains of P. larvae through their diet by examining the ascorbyl radical (A) to ascorbate anion (AH¯) ratio.
View Article and Find Full Text PDFThe influence of manganese modification on the spectroscopic features of manganese-doped CeO systems synthesized by the microwave-assisted hydrothermal route and their correlation with the presence of O defective structures were verified, focusing on their interaction with poisonous atmospheres. Raman and electron paramagnetic resonance studies confirmed the presence of defective clusters formed by dipoles and/or quadrupoles. The number of paramagnetic species was found to be inversely proportional to the doping concentration, resulting in an increase in the Mn signal, likely due to the reduction of Mn species after the interaction with CO.
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