The transformation of crystalline silicon to amorphous silicon during ball milling was quantitatively measured by x-ray diffraction and electrochemical methods. Amorphous silicon was found to form rapidly from the very initial stages of ball milling. Simultaneously, the grain size of the crystalline silicon phase decreased.
View Article and Find Full Text PDFTo improve the energy density of LiFePO (LFP) cathode materials for Li-ion cells, we have utilized a modified mechanofusion method for preparing micrometer-sized LFP/C composite flake particles. The resulting flake particle morphology resulted in improved packing efficiency, enabling an electrode porosity of 14% to be achieved at high loadings, which represents a volumetric energy density increase of 28% compared to conventional LFP. Furthermore, LFP/C flake composites electrodes were found to have a higher coulombic efficiency, a reduced voltage-polarization, and a greatly reduced charge transfer resistance compared to conventional LFP electrodes.
View Article and Find Full Text PDFIn this study, new insights into the all-dry synthesis of the LiNiMnCoO (NMC622) cathode using a single-phase rock-salt (RS) oxide precursor are provided. It was found that use of a larger amount of excess Li content not only can enhance the electrochemical performance of NMC made from the RS-precursor but also increase the degree of homogeneity of the NMC cathode material. XRD analysis showed that lithiation of the RS-precursor (, formation of the O3-phase) starts at a higher synthesis temperature (∼450 °C) than that is required when using a hydroxide precursor (HP) and lithium carbonate (∼350 °C).
View Article and Find Full Text PDFBackground: Due to rapid spread, the Omicron variant has become the dominant SARS-CoV-2 variant responsible for infections worldwide. We present the first detection of the Omicron variant in Croatia which resulted in rapid cross-border spreading.
Methods: Whole-genome sequencing was performed using the Illumina MiniSeq sequencing system.