Assembly of galvinoxyl doped in polymer-fullerene photovoltaic blends.

Galvinoxyl (Gx) is a stable free radical used as a dopant in active layers of organic solar cells. Here, the nanoscale arrangement of Gx molecules in a composite of the PCDTBT polymer and modified C fullerene, PCBM, was studied using a two-pulse electron spin echo (ESE) technique. The results show that the Gx molecules assemble into clusters, which can be described by the model of 8 molecules on the surface of a sphere with a radius of 2.

Fast Recombination of Charge-Transfer State in Organic Photovoltaic Composite of P3HT and Semiconducting Carbon Nanotubes Is the Reason for Its Poor Photovoltaic Performance.

Although the photovoltaic performance of the composite of poly-3-hexylthiophene (P3HT) with semiconducting single-walled carbon nanotubes (s-SWCNT) is promising, the short-circuit current density is much lower than that for typical polymer/fullerene composites. Out-of-phase electron spin echo (ESE) technique with laser excitation of the P3HT/s-SWCNT composite was used to clarify the origin of the poor photogeneration of free charges. The appearance of out-of-phase ESE signal is a solid proof that the charge-transfer state of P3HT/s-SWCNT is formed upon photoexcitation and the electron spins of P3HT and s-SWCNT are correlated.

Geminate recombination in organic photovoltaic blend PCDTBT/PCBM studied by out-of-phase electron spin echo spectroscopy.

The key process in organic solar cell operation is charge separation under light illumination. Due to the low dielectric constant of organic materials, the Coulomb attraction energy within the interfacial charge-transfer state (CTS) is larger than the thermal energy. Understanding the mechanism of charge separation at the organic donor/acceptor interface still remains a challenge and requires knowledge of the CTS temporal evolution.

A Weakly Antiferromagnetically Coupled Biradical Combining Verdazyl with Nitronylnitroxide Units.

An antiferromagnetically (AFM) coupled biradical based on oxoverdazyl and nitronylnitroxide was synthesized in 46 % yield using Sonogashira coupling. The obtained heterobiradical evidenced distinct properties of both radical entities in solution. Depending on the solvent, the prepared biradical crystallized in two different forms.

Light-induced charge separation in a P3HT/PCBM composite as studied by out-of-phase electron spin echo spectroscopy.

A composite material of semiconducting polymer P3HT and fullerene derivative PCBM was studied by means of electron spin echo (ESE) spectroscopy. The out-of-phase ESE signal was observed under laser irradiation of the composite at low temperature. We assume that during the charge separation process firstly the spin-correlated radical pairs in the singlet-polarized spin state are formed, and then the net polarization of radical pairs arises due to spin evolution.