Effects of Surface Chemical Modification by Ethoxysilanes on the Evolution of 3D Structure and Composition of Porous Monoliths Consisting of Alumina Hydroxide Nanofibrils in the Temperature Range 25-1700 °C.

Bulk nanomaterials with an open porosity offer exciting prospects for creating new functional materials for various applications in photonics, IR-THz optics, metamaterials, heterogeneous photocatalysis, monitoring and cleaning toxic impurities in the environment. However, their availability is limited by the complexity of controlling the process of synthesis of bulk 3D nanostructures with desired physicochemical and functional properties. In this paper, we performed a detailed analysis of influence of a silica monolayer chemically deposited on the surface of a monolithic ultraporous nanostructure, consisting of a 3D nanofibril network of aluminum oxyhydroxide, on the evolution of structure and morphology, chemical composition and phase transformations after heat treatment in the temperature range of 20-1700 °C.

Polarization control of terahertz radiation from two-color femtosecond gas breakdown plasma.

We individually control polarizations of 800 and 400 nm beams, which form a two-color femtosecond plasma filament in air irradiating a linear-to-elliptical THz signal. We detected a threshold-like appearance of THz ellipticity at the angle of ∼85° between the fundamental and second-harmonic field polarization directions. The simulations confirm the abrupt change of THz polarization and reveal that the weak ellipticity of the second harmonic is sufficient to generate essentially elliptical THz radiation.

Impact of the dipole contribution on the terahertz emission of air-based plasma induced by tightly focused femtosecond laser pulses.

The present paper studies the generation mechanism of terahertz (THz) radiation from tightly focused femtosecond laser pulses in a gas medium. We measured the angular radiation pattern under different focusing conditions and observed that, with the deepening of focus, the angular radiation pattern changes and optical-to-THz conversion efficiency increases. The analysis of the observed phenomena led to the assumption that the dipole radiation prevails in most cases despite the existing conception regarding the dominating role of the quadrupole mechanism of radiation.

Ultrabroad Terahertz Spectrum Generation from an Air-Based Filament Plasma.

We have solved the long-standing problem of the mechanism of terahertz (THz) generation by a two-color filament in air and found that both neutrals and plasma contribute to the radiation. We reveal that the contribution from neutrals by four-wave mixing is much weaker and higher in frequency than the distinctive plasma lower-frequency contribution. The former is in the forward direction while the latter is in a cone and reveals an abrupt down-shift to the plasma frequency.

Possibility of direct estimation of terahertz pulse electric field.

In this Letter, we introduce a new method of estimation of the terahertz (THz) field amplitude. This method uses second-harmonic generation (SHG) in the presence of THz and DC fields in gaseous media. We take into account contributions from both nonionized molecules and free plasma electrons to the nonlinear process of SHG.