Diffusion-limited kinetics is a key mechanistic debate when consecutive photoelectron transfer (conPET) is discussed in photoredox catalysis. In-situ generated organic photoactive radicals can access catalytic systems as reducing as alkaline metals that can activate remarkably stable bonds. However, in many cases, the extremely short-lived transient nature of these doublet state open-shell species has led to debatable mechanistic studies, hindering adoption and development.
View Article and Find Full Text PDFJMIR Pediatr Parent
January 2025
Background: Globally, 10% of pregnant women and 13% of postpartum women experience mental disorders. In Bangladesh, nearly 50% of mothers face common mental disorders, but mental health services and trained professionals to serve their needs are scarce. To address this, the government of Bangladesh's Non-Communicable Disease Control program initiated "Wellbeing Centers," telemental health services in selected public hospitals.
View Article and Find Full Text PDFThis study aims to suggest and empirically evaluate a conceptual framework that investigates the association of career self-efficacy with career intentions, emphasizing on the specific and sequential mediating mechanisms of two psychological constructs: person-environment (P-E) fit and career attitudes. Relationships among the constructs were hypothesized based on the relevant literature and were examined with AMOS and SPSS Process Macro using survey data collected from a sample of 341 job seekers in Bangladesh. Results showed that P-E fit and career attitudes each partially mediated the relationship between career self-efficacy and career intentions.
View Article and Find Full Text PDFCholera rapid diagnostic tests (RDTs) are vulnerable to virulent bacteriophage predation. We hypothesized that an enhanced cholera RDT that detects the common virulent bacteriophage ICP1 might serve as a proxy for pathogen detection. We previously developed a monoclonal antibody (mAb) to the ICP1 major capsid protein.
View Article and Find Full Text PDFCovalent integration of polymers and porous organic frameworks (POFs), including metal-organic frameworks (MOFs), covalent organic frameworks (COFs) and hydrogen-bonded organic frameworks (HOFs), represent a promising strategy for overcoming the existing limitations of traditional porous materials. This integration allows for the combination of the advantages of polymers, i.e.
View Article and Find Full Text PDF