Publications by authors named "M Medarde"

Vacancies in solid-state physics are underexplored in materials with strong electron-electron correlations. Recent research on the Ir-Sb binary system revealed an extended buckled-honeycomb vacancy (BHV) order. Superconductivity arises by suppressing BHV ordering through high-pressure growth with excess Ir atoms or Rh substitution, yet the superconducting pairing nature remains unknown.

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The two-dimensional kagome lattice is an experimental playground for novel physical phenomena, from frustrated magnetism and topological matter to chiral charge order and unconventional superconductivity. A newly identified kagome superconductor, TaVSi has recently gained attention for possessing a record high critical temperature,  = 7.5 K for kagome metals at ambient pressure.

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Strongly-correlated transition-metal oxides are widely known for their various exotic phenomena. This is exemplified by rare-earth nickelates such as LaNiO, which possess intimate interconnections between their electronic, spin, and lattice degrees of freedom. Their properties can be further enhanced by pairing them in hybrid heterostructures, which can lead to hidden phases and emergent phenomena.

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The elastic moduli provide unique insights into the thermodynamics of quantum materials, particularly into the symmetries broken at their phase transition. Here, we present a workflow to carve crystalline resonators via focused ion beam milling from small and oddly shaped crystals unsuitable for traditional measurements of elasticity. The accuracy of this technique is first established in silicon.

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Large quantities of high-purity NHCrF have been synthesized using a wet-chemical method, and its structural chemistry and magnetic properties are investigated in detail for the first time. NHCrF is a tetragonal fluoroperovskite that displays an ordering of the ammonium (NH) groups at room temperature and C-type orbital ordering. The ammonium groups order and display distinct signs of hydrogen bonds to nearby fluoride anions by buckling the Cr-F-Cr angle away from 180°.

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