Peroxo heteroligand vanadates(V): synthesis, spectra-structure relationships, and stability toward decomposition.

Effect of heteroligands (L) on the properties of vanadium peroxides was investigated by preparing a number of peroxovanadium complexes, which were characterized by analysis, IR, UV/V and NMR spectra. X-ray structures for some were obtained. The vanadates(V) contain the cation M(I) = Na, K, NH4, Rb or Cs.