Exfoliation of two-dimensional polymer single crystals into thin sheets and investigations of their surface structure by high-resolution atomic force microscopy.

The acid-assisted wet-chemical and the adhesive-tape induced micromechanical exfoliation of differently sized single crystals of a 2D polymer (approx. 20 μm and 100 μm) is shown to result in thin sheet stacks. Tuning of the thickness is achieved via duration and frequency of the exfoliation, respectively.

Decorating the Edges of a 2D Polymer with a Fluorescence Label.

This work proves the existence and chemical addressability of defined edge groups of a 2D polymer. Pseudohexagonally prismatic single crystals consisting of layered stacks of a 2D polymer are used. They should expose anthracene-based edge groups at the six (100) but not at the two pseudohexagonal (001) and (001̅) faces.

Scalable Synthesis of Two-dimensional Polymer Crystals and Exfoliation into Nanometer-thin Sheets.

Two-dimensional materials have moved into the spotlight of researchers. The isolation of single graphene sheets has shown that restricted dimensionality can lead to interesting properties. Bottom-up synthesis of organic, covalently-bonded structures is, however, still challenging.

Gram-scale synthesis of two-dimensional polymer crystals and their structure analysis by X-ray diffraction.

The rise of graphene, a natural two-dimensional polymer (2DP) with topologically planar repeat units, has challenged synthetic chemistry, and has highlighted that accessing equivalent covalently bonded sheet-like macromolecules has, until recently, not been achieved. Here we show that non-centrosymmetric, enantiomorphic single crystals of a simple-to-make monomer can be photochemically converted into chiral 2DP crystals and cleanly reversed back to the monomer. X-ray diffraction established unequivocal structural proof for this synthetic 2DP, which has an all-carbon scaffold and can be synthesized on the gram scale.