Implementing magnetically-active Sn-based nanocomposites in hexavalent chromium removal from drinking water.

A novel nanocomposite consisting of FeO-loaded tin oxyhydroxy-chloride is demonstrated as an efficient adsorbent for the removal of hexavalent chromium in compliance to the new drinking water regulation. This study introduces a continuous-flow production of the nanocomposite through the separate synthesis of (i) 40 nm FeO nanoparticles and (ii) multilayered spherical arrangements of a tin hydroxy-chloride identified as abhurite, before the application of a wet-blending process. The homogeneous distribution of FeO nanoparticles on the abhurite's morphology, features nanocomposite with magnetic response whereas the 10 % loaded nanocomposite preserves a Cr(VI) uptake capacity of 7.

Se(IV)/Se(VI) adsorption mechanisms on natural and on Ca-modified zeolite for Mediterranean soils amended with the modified zeolite: prospects for agronomic applications.

In the present study, the ability of a modified CaCl zeolite (Ca-Z) to both increase Se(IV) availability and restrict Se(VI) mobility in soils is examined. As it was resulted from batch experiments and verified by X-ray absorption fine structure (XAFS) and X-ray fluorescence (XRF) spectroscopies, higher amounts of both Se species adsorbed on Ca-Z compared to natural zeolite (Z-N) forming outer-sphere complexes while the oxidation state did not alter during agitation of samples. Thereafter, Ca-Z was incorporated in six Greek soils, divided into acid and alkaline, at a 20% (w/w) rate and a series of equilibrium batch experiments were performed with soils alone and soils-Ca-Z mixtures to investigate sorption and desorption processes and mechanisms.

Probing the structural role of Cr in stabilized tannery wastes with X-ray absorption fine structure spectroscopy.

The effective stabilization of tannery sludge wastes is explored using X-Ray Absorption Fine Structure (XAFS) spectroscopies. Solidification of the Cr-rich waste was realized via vitrification of the incinerated sludge with silica and flux agents. It is demonstrated that the effective reduction of Cr(VI) and the structural role of Cr are strongly modulated by the chemical composition of the waste.

Crystalline and amorphous calcium carbonate as structural components of the Calappa granulata exoskeleton.

The exoskeleton of crustaceans consists of chitin biopolymers where the embedded inorganic biominerals, mainly CaCO, affect strongly its mechanical properties. Raman and Near Edge X-ray Absorption Fine Structure (NEXAFS) spectroscopies and Transmission Electron Microscopy (TEM) are applied to investigate the CaCO structure in various parts of the Calappa granulata crab exoskeleton. The shape of the main Raman peak of CaCO reveals the presence of two phases which are identified as calcite and amorphous calcium carbonate (ACC).

Enhanced thermal conductivity in percolating nanocomposites: a molecular dynamics investigation.

In this work we present a molecular dynamics investigation of thermal transport in a silica-gallium nitride nanocomposite. A surprising enhancement of the thermal conductivity for crystalline volume fractions larger than 5% is found, which cannot be predicted by an effective medium approach, not even including percolation effects, the model systematically leading to an underestimation of the effective thermal conductivity. The behavior can instead be reproduced if an effective volume fraction twice larger than the real one is assumed, which translates into a percolation effect surprisingly stronger than the usual one.