Crossing the Frontier of Validity of the Material Time Approach in the Aging of a Molecular Glass.

We studied the physical aging of glycerol in response to upward temperature steps of amplitude ranging from 0.3 to 18 K. This was done using a specially designed experimental setup allowing quick heating of a liquid film while measuring the evolution of its dielectric properties.

Orientational dynamics in supercooled glycerol computed from MD simulations: self and cross contributions.

The orientational dynamics of supercooled glycerol is probed using molecular dynamics simulations for temperatures ranging from 323 K to 253 K, through correlation functions of first and second ranks of Legendre polynomials, pertaining respectively to dielectric spectroscopy (DS) and depolarized dynamic light scattering (DDLS). The self, cross, and total correlation functions are compared with relevant experimental data. The computations reveal the low sensitivity of DDLS to cross-correlations, in agreement with what is found in experimental work, and strengthen the idea of directly comparing DS and DDLS data to evaluate the effect of cross-correlations in polar liquids.

Non-linear physical aging of supercooled glycerol induced by large upward ideal temperature steps monitored through cooling experiments.

The physical aging of supercooled glycerol induced by upward temperature steps of amplitude reaching 45 K was studied by a new method consisting in heating a micrometer-thick liquid film at a rate of up to 60 000 K/s, holding it at a constant high temperature for a controlled duration before letting it quickly cool down to the initial temperature. By monitoring the final slow relaxation of the dielectric loss, we were able to obtain quantitative information on the liquid response to the initial upward step. The so-called TNM (Tool-Narayanaswamy-Moynihan) formalism provided a good description of our observations despite the large distance from equilibrium, provided that different values of the nonlinearity parameter were used for the cooling phase and for the (much further from equilibrium) heating phase.

How dirt cones form on glaciers: Field observation, laboratory experiments, and modeling.

Dirt cones are meter-scale structures encountered at the surface of glaciers, which consist of ice cones covered by a thin layer of ashes, sand, or gravel, and which form naturally from an initial patch of debris. In this article, we report field observations of cone formation in the French Alps, laboratory-scale experiments reproducing these structures in a controlled environment, and two-dimensional discrete-element-method-finite-element-method numerical simulations coupling the grain mechanics and thermal effects. We show that cone formation originates from the insulating properties of the granular layer, which reduces ice melting underneath as compared to bare ice melting.

Onset of Glacier Tables.

A glacier table consists of a rock supported by a slender column of ice and form naturally on glaciers. We investigate the onset of their formation at a smaller scale in a controlled environment. Depending on the size and thermal conductivity of a cap, it can either form of a table standing on an ice foot, or sink into the ice block.