Ultra-high vacuum conditions are ideal for the study of trapped ions. They offer an almost perturbation-free environment, where ions confined in traps can be studied for extended periods of time-facilitating precision measurements and allowing infrequent events to be observed. However, if one wishes to study processes involving molecular ions, it is important to consider the effect of blackbody radiation (BBR).
View Article and Find Full Text PDFRadicals are prevalent in gas-phase environments such as the atmosphere, combustion systems, and the interstellar medium. To understand the properties of the processes occurring in these environments, it is helpful to study radical reaction systems in isolation-thereby avoiding competing reactions from impurities. There are very few methods for generating a pure beam of gas-phase radicals, and those that do exist involve complex setups.
View Article and Find Full Text PDFRev Sci Instrum
December 2019
A new optical system is introduced for the imaging of Coulomb crystals held in a cryogenic ion trap where there are space limitations preventing the placement of an objective close to the fluorescing ions. The optical system features an off-axis parabolic (OAP) mirror relay microscope that will serve to acquire images of a lattice of fluorescing ions confined within an ultra-high-vacuum vessel operating at temperatures below 10 K. We report that the OAP mirror relay setup can resolve features smaller than the separation between neighboring ions in Coulomb crystals.
View Article and Find Full Text PDFWe present studies on the thermalisation of H3+ ions in a cold He/Ar/H2 plasma at temperatures 30-70 K. We show that we are able to generate a rotationally thermalised H3+ ensemble with a population of rotational and nuclear spin states corresponding to a particular ion translational temperature. By varying the para-H2 fraction used in the experiment we are able to produce para-H3+ ions with fractional populations higher than those corresponding to thermodynamic values.
View Article and Find Full Text PDFIn Zeeman deceleration, only a small subset of low-field-seeking particles in the incoming beam possess initial velocities and positions that place them within the phase-space acceptance of the device. In order to maximize the number of particles that are successfully decelerated to a selected final velocity, we seek to optimize the phase-space acceptance of the decelerator. Three-dimensional particle trajectory simulations are employed to investigate the potential benefits of using a covariance matrix adaptation evolutionary strategy (CMA-ES) optimization method for decelerators longer than 12 stages and for decelerating species other than H atoms.
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