Plant cell wall (CW)-like soft materials, referred to as artificial CWs, are composites of assembled polymers containing micro-/nanoparticles or fibers/fibrils that are designed to mimic the composition, structure, and mechanics of plant CWs. CW-like materials have recently emerged to test hypotheses pertaining to the intricate structure-property relationships of native plant CWs or to fabricate functional materials. Here, research on plant CWs and CW-like materials is reviewed by distilling key studies on biomimetic composites primarily composed of plant polysaccharides, including cellulose, pectin, and hemicellulose, as well as organic polymers like lignin.
View Article and Find Full Text PDFLaMoO is acknowledged as an exceptional oxide ion conductor. It undergoes a reversible phase transition around 580 °C from the nonconductive low-temperature monoclinic α-LaMoO phase to the highly conductive high-temperature cubic β-LaMoO phase. In addition, LaMoO demonstrates complex chemistry under reducing conditions.
View Article and Find Full Text PDFOur conventional approach to health care tends to separate patients' health by body system, treating each independently and "efficiently"-e.g., minimal time with a provider, reliance on medications, and little investment to support behavioral and lifestyle improvements.
View Article and Find Full Text PDFMelilite-type gallates of general formula REAEGaO are of interest for their ability to host mobile interstitial oxide ions in [GaO] layers. The crystal structure of CaGaO is closely related to melilite, with [GaO] layers stacked in a more complex way to accommodate an additional 0.5 interlayer cations per formula unit, suggesting the potential for similar oxide ion conduction behavior.
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