Deciding on the implementation or modification of steps in daily clinical care is a nuanced process that demands careful evaluation. This is crucial not only for selecting the most appropriate solution but also for achieving the best treatment outcome. Thus, implementing a workflow for treating cleft lip and/or palate patients with a presurgical orthodontic cleft-covering plate needs to consider objective factors, prioritized from most to least important: safety and quality level, user-friendliness, feasibility, and, finally, efficiency and cost.
View Article and Find Full Text PDFThe objective of this study was to present a methodology and manufacturing workflow for non-invasive ventilation interfaces (NIV) for neonates and small infants. It aimed to procure a fast and feasible solution for personalized NIV produced in-house with the aim of improving fit and comfort for the patient. Three-dimensional scans were obtained by means of an intraoral (Trios 3) and a facial scanner (3dMd Flex System).
View Article and Find Full Text PDFPorphyrins are key elements in organic-inorganic hybrid systems for a wide range of applications. Understanding their interaction with the substrate gives a handle on structural and electronic device properties. Here we investigate a single transition-metal porphyrin, namely Co(ii)-tetraphenylporphyrin (CoTPP), on the MgO(100) surface and the effect of multilayer film formation within hybrid density-functional theory and many-body perturbation theory.
View Article and Find Full Text PDFPhys Chem Chem Phys
February 2020
Thin porphyrin films as employed in modern optical devices or photovoltaic applications show deviating electronic and optical properties from the gasphase species. Any understanding of the physical origin may pave way to a specific engineering of these properties via ligand or substituent control. Here we investigate the impact of crystallization of prototypical porphyrins on the electronic levels and optical properties in the framework of density functional theory and many-body perturbation theory.
View Article and Find Full Text PDFElectron attachment and solvation at ice structures are well-known phenomena. The energy liberated in such events is commonly understood to cause temporary changes at such ice structures, but it may also trigger permanent modifications to a yet unknown extent. We determine the impact of electron solvation on DO structures adsorbed on Cu(111) with low-temperature scanning tunneling microscopy, two-photon photoemission, and ab initio theory.
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