Publications by authors named "M Banski"

In this paper, the study of surface modification of two-dimensional (2D), non-luminescent CdS nanoplates (NPLs) by thiol-containing ligands is presented. We show that a process of twophase transfers with appropriate ligand exchange transforms non-luminescent NPLs into spherical CdS nanoparticles (NPs) exhibiting a blue photoluminescence with exceptionally high quantum yield ~90%. In the process, transfer from inorganic solvent to water is performed, with appropriately selected ligand molecules and pH values (forward phase transfer), which produces NPs with modified size and shape.

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Optical imaging holds great promise for the early-stage detection of diseases. It plays an important role in the process of protecting the patient's health. Most of the organic dyes suffer due to photobleaching, light scattering, short light penetration depth, and autofluorescence of specimen, thus, need to be replaced with alternative nanoprobes emitting light in the optical biological window (700-1350 nm).

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In recent years, numerous protocols for nanoplatelet synthesis have been developed. Here, we present a facile, one-pot method for controlling cadmium sulfide (CdS) nanoparticles' shape that allows for obtaining zero-dimensional, one-dimensional, or two-dimensional structures. The proposed synthesis protocol is a simple heating-up approach and does not involve any inconvenient steps such as injection and/or pouring the precursors at elevated temperatures.

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Article Synopsis
  • The study explores how pH levels affect the optical characteristics and stability of quantum dots (QDs) by modifying hydrophobic CdSe/CdS QDs with 3-mercaptopropionic acid.
  • The best functionalization efficiency (45%) and preservation of photoluminescence (PL) occurred under acidic conditions, even though the PL was significantly lower than that of hydrophobic QDs.
  • The research indicates that QDs maintain strong PL at specific pH levels regardless of the initial pH during the modification process, with PL intensity behaving differently for QDs modified under various pH conditions over a broad pH range (2-12).
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We proposed to exploit phosphomolybdic acid (PMA) as a cost-efficient MoO source for combined spin-coating/sputtering/spin-coating deposition of a MoO /Au/MoO (MAM) composite electrode. The bottom PMA layer provides perfect wetting conditions for ultrathin Au film sputtering and prevents the formation of gold islands on the glass surface, while the top PMA layer helps to reduce light reflection. By optimizing the thickness of ultrathin Au films and PMA layers, we achieved maximum transmittance of 79% at 550 nm and a sheet resistance of only 22 Ω sq which is comparable to the resistance of ITO substrates (20 Ω sq).

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