Synthetic manifestation of trinitro-pyrazolo-2-1,2,3-triazoles (TNPT) as insensitive energetic materials.

This study showcases the design and development of a facile method for synthesizing trinitro-pyrazolo-triazole (TNPT) and its derivatives. The synthesized compounds are analysed using multinuclear NMR [H, C, and N] and HRMS analyses. Furthermore, X-ray diffraction studies confirm the structure of some TNPT derivatives.

Polynitro--aryl-C-nitro-pyrazole/imidazole Derivatives: Thermally Stable-Insensitive Energetic Materials.

A wide array of methoxy-substituted-polynitro-aryl-pyrazole/imidazoles with readily oxidizable -NH/NO/NHNO/diazo functional groups is synthesized. Single crystal X-ray diffraction (XRD) analysis confirms the molecular structure of the compounds. Energetic properties of the synthesized compounds are determined by theoretical and experimental studies.