Single-phase epitaxial HfZrO films with non-centrosymmetric orthorhombic structure have been grown directly on electrode-free corundum (α-AlO) substrates by pulsed laser deposition. A combination of high-resolution X-ray diffraction and X-ray absorption spectroscopy confirms the epitaxial growth of high-quality films belonging to the 2 space group, with [111] out-of-plane orientation. The surface of a 7-nm-thick sample exhibits an atomic step-terrace structure with a corrugation of the order of one atomic layer, as proved by atomic force microscopy.
View Article and Find Full Text PDFAurivillius compounds with the general formula (BiO)(ABO) are a highly topical family of functional layered oxides currently under investigation for room-temperature multiferroism. A chemical design strategy is the incorporation of magnetically active BiMO units (M: Fe, Mn, Co …) into the pseudo-perovskite layer of known ferroelectrics like BiTiO, introducing additional oxygen octahedra. Alternatively, one can try to directly substitute magnetic species for Ti in the perovskite slab.
View Article and Find Full Text PDFIn this Letter, we propose a simple model that can provide a combined explanation of the Z→bb[over ¯] forward-backward asymmetry, the Cabibbo angle anomaly (CAA), τ→μνν and b→sℓ^{+}ℓ^{-} data. This model is obtained by extending the standard model (SM) by two heavy vectorlike quarks (an SU(2)_{L} doublet (singlet) with hypercharge -5/6 (-1/3), two new scalars (a neutral and a singly charged one), and a gauged L_{μ}-L_{τ} symmetry. The mixing of the new quarks with the SM ones, after electroweak symmetry breaking, does not only explain Z→bb[over ¯] data, but also generates a lepton flavor universal contribution to b→sℓ^{+}ℓ^{-} transitions.
View Article and Find Full Text PDFIn this work, we investigated the processing-microstructure-property relationships for magnetoelectric (ME) particulate composites consisting of hard ferromagnetic CoFeO (CFO) particles dispersed in a Nb-doped PbZrTiO (PZT) soft ferroelectric matrix. Several preparation steps, namely PZT powder calcination, PZT-CFO mixture milling and composite sintering were tailored and a range of microstructures was obtained. These included open and closed porosities up to full densification, PZT matrices with decreasing grain size across the submicron range down to the nanoscale and well dispersed CFO particles with bimodal size distributions consisting of submicron and micron sized components with varying weights.
View Article and Find Full Text PDFLi- and Ta-modified K 0.5 Na 0.5 NbO 3 compounds are among the most promising lead-free ferroelectrics for high-sensitivity piezoelectric ceramic materials, and are potentially capable of replacing Pb(Zr,Ti)O 3 .
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