Dual-Column Stopped-Flow GC Method for Quantification of Permanent Gases, Water, and Organic Acids from a Single Injection.

Analysis of permanent gases and organic acids is typically performed with separate methods due to challenges in achieving sufficient resolution when using GC columns that are chemically compatible with acids. We developed a method to analyze samples containing high levels of water, organic acids, oxygenates, and permanent gases (CO, CO, and CH) using a single injection. Resolution is achieved using two columns: (1) an HP-FFAP column resistant to water and acids, which separates compounds based on hydrogen-bonding affinity, and (2) a GS-CarbonPLOT column capable of separating permanent gases.