Mechanically robust and stretchable organic solar cells plasticized by small-molecule acceptors.

Emerging wearable devices would benefit from integrating ductile photovoltaic light-harvesting power sources. In this work, we report a small-molecule acceptor (SMA), also known as a non-fullerene acceptor (NFA), designed for stretchable organic solar cell (-OSC) blends with large mechanical compliance and performance. Blends of the organosilane-functionalized SMA BTP-Si4 with the polymer donor PNTB6-Cl achieved a power conversion efficiency (PCE) of >16% and ultimate strain (ε) of >95%.

Polymerized-Small-Molecule Acceptors Featuring Siloxane-Terminated Side Chains for Mechanically Robust All-Polymer Solar Cells.

Flexible and stretchable organic solar cells (OSCs) show great promise in wearable and stretchable electronic applications. However, current high-performance OSCs consisting of polymer donors (PDs) and small-molecule acceptors (SMAs) face significant challenges in achieving both high power conversion efficiency (PCE) and excellent stretch-ability. In this study, we synthesized a new polymerized-small-molecule acceptor (P-SMA) PY-SiO featuring siloxane-terminated side chains and compared its photovoltaic and mechanical performance to that of the reference PY-EH with ethylhexyl-terminated side chains.

Zirconium Doping to Enable High-Efficiency and Stable CsPbIBr All-Inorganic Perovskite Solar Cells.

All-inorganic wide-bandgap perovskite CsPbIBr has attracted much attention because of its inherent thermal stability and ideal bandgap for the front subcell of tandem solar cells (TSCs). However, the low power conversion efficiency (PCE) and poor moisture stability of CsPbIBr still restrict its future commercialization. Herein, zirconium tetrachloride (ZrCl) was doped into CsPbIBr films to modulate the crystal growth and improve the film quality.

Chlorinated Narrow Bandgap Polymer Suppresses Non-Radiative Recombination Energy Loss Enabling Perylene Diimides-Based Organic Solar Cells Exceeding 10% Efficiency.

The scarcity of narrow bandgap donor polymers matched with perylene diimides (PDI)-based nonfullerene acceptors (NFAs) hinders improvement of the power conversion efficiency (PCE) value of organic solar cells (OSCs). Here, it is reported that a narrow bandgap donor polymer PDX, the chlorinated derivative of the famous polymer donor PTB7-Th, blended with PDI-based NFA boosts the PCE value exceeding 10%. The electroluminescent quantum efficiency of PDX-based OSCs is two orders of magnitude higher than that of PTB7-Th-based OSCs;therefore, the nonradiative energy loss is 0.

Intrinsically Stretchable Organic Solar Cells with Simultaneously Improved Mechanical Robustness and Morphological Stability Enabled by a Universal Crosslinking Strategy.

Developing intrinsically stretchable organic solar cells (OSCs) with excellent mechanical robustness and long-term operation stability is highly demanded for practical applications. Here, the representative PM6/Y6 active layer film, crosslinked by a photo-crosslinkable small molecule 2,6-bis(4-azidobenzylidene)cyclohexanone (BAC) containing azide groups, exhibits a significantly enhanced stretchability of 18% and toughness of 6.94 MJ m , compared to non-crosslinked film (stretchability of 4.

Rearranging the Phase Distribution of Quasi-2D Perovskite for Efficient and Narrow Emission Perovskite Light-Emitting Diodes.

Quasi-2D perovskite light-emitting diodes (PeLEDs) have attracted significant attention for their promising light-emitting applications. However, quasi-2D perovskite films typically consist of a broad phase distribution and small grains with a large surface area to volume ratio, leading to inferior color purities and higher defect densities. Herein, a bifunctional additive ((l)-tryptophan bromide, l-TrpBr) was introduced into a quasi-2D perovskite film.

Over 21% Efficiency Stable 2D Perovskite Solar Cells.

Owing to their insufficient light absorption and charge transport, 2D Ruddlesden-Popper (RP) perovskites show relatively low efficiency. In this work, methylammonium (MA), formamidinum (FA), and FA/MA mixed 2D perovskite solar cells (PSCs) are fabricated. Incorporating FA cations extends the absorption range and enhances the light absorption.