The effect of preparation methods on the thermal and chemical reducibility of Cu in Cu-Al oxides.

The influence of the preparation methods on the physicochemical properties of Cu and Al oxides was studied. Four different preparation methods were used to synthesize the oxides (catalysts): co-precipitation by the hydrotalcite precursor route (CuAl-HT-c), the solid-state reaction route (CuAl-s), the physical mixing of the oxides (CuAl-o), and individual oxide precipitation followed by physical mixing (CuAl-p). Chemical analysis, X-ray diffraction and textural analysis results of the precursor CuAl-HT-c showed that the respective preparation method is efficient to obtain the hydrotalcite phase with high purity as well as generating a mixed oxide with the greatest surface area among all of the catalysts in this study.

Synthesis and characterization of terephthalate-intercalated NiAl layered double hydroxides with high Al content.

Terephthalate-intercalated nickel-aluminum layered double hydroxides (LDHs) were prepared by a co-precipitation method, with nominal x values in the general formula Ni((1-x))Al(x)(OH)(2)(C(8)H(4)O(4))(x/2) in the range 0.3-0.8.