Select volatile organic compounds (VOCs) were measured in the vicinity of chemical facilities and other operations in the Rubbertown industrial area of Louisville, Kentucky (USA) using modified EPA Methods 325A/B passive sampler tubes. Two-week, time-integrated passive samplers were deployed at ten sites which were aggregated into three site groups of varying distances from the Rubbertown area facilities. In comparison to canister data from 2001 to 2005, two of the sites suggested generally lower current VOC levels.
View Article and Find Full Text PDFUnlabelled: Select volatile organic compounds (VOCs) in ambient air were measured at four fenceline sites at a petroleum refinery in Whiting, IN, using modified EPA Method 325 A/B with passive tubes and EPA Compendium Method TO-15 with canister samplers. One-week, time-integrated samplers were deployed for 8 weeks with tubes and canister samplers deployed in duplicate. Good precision was obtained from the duplicate tubes (<7%) and duplicate canisters (≤10%) for BTEX, perchloroethylene, and styrene.
View Article and Find Full Text PDFObjective: Exposure to mobile source emissions is nearly ubiquitous in developed nations and is associated with multiple adverse health outcomes. There is an ongoing need to understand the specificity of traffic exposure associations with vascular outcomes, particularly in individuals with cardiovascular disease.
Approach And Results: We performed a cross-sectional study using 2124 individuals residing in North Carolina, United States, who received a cardiac catheterization at the Duke University Medical Center.
A sample integrity evaluation and an interlaboratory comparison were conducted in application of U.S. Environmental Protection Agency (EPA) Methods 325A and 325B for diffusively monitoring benzene and other selected volatile organic compounds (VOCs) using Carbopack X sorbent tubes.
View Article and Find Full Text PDFUnlabelled: Select volatile organic compounds (VOCs) were measured in the vicinity of a petroleum refinery and related operations in South Philadelphia, Pennsylvania, USA, using passive air sampling and laboratory analysis methods. Two-week, time-integrated samplers were deployed at 17 sites, which were aggregated into five site groups of varying distances from the refinery. Benzene, toluene, ethylbenzene, and xylene isomers (BTEX) and styrene concentrations were higher near the refinery's fenceline than for groups at the refinery's south edge, mid-distance, and farther removed locations.
View Article and Find Full Text PDFUnlabelled: A pilot study was conducted in application of the U.S. Environmental Protection Agency (EPA) Methods 325A/B variant for monitoring volatile organic compounds (VOCs) near two oil and natural gas (ONG) production well pads in the Texas Barnett Shale formation and Colorado Denver-Julesburg Basin (DJB), along with a traffic-dominated site in downtown Denver, CO.
View Article and Find Full Text PDFBackground: The relationship between traffic-related air pollution (TRAP) and risk factors for cardiovascular disease needs to be better understood in order to address the adverse impact of air pollution on human health.
Objective: We examined associations between roadway proximity and traffic exposure zones, as markers of TRAP exposure, and metabolic biomarkers for cardiovascular disease risk in a cohort of patients undergoing cardiac catheterization.
Methods: We performed a cross-sectional study of 2,124 individuals residing in North Carolina (USA).
Two deterministic models (US EPA's Office of Pesticide Programs Residential Standard Operating Procedures (OPP Residential SOPs) and Draft Protocol for Measuring Children's Non-Occupational Exposure to Pesticides by all Relevant Pathways (Draft Protocol)) and four probabilistic models (CARES(®), Calendex™, ConsExpo, and SHEDS) were used to estimate aggregate residential exposures to pesticides. The route-specific exposure estimates for young children (2-5 years) generated by each model were compared to evaluate data inputs, algorithms, and underlying assumptions. Three indoor exposure scenarios were considered: crack and crevice, fogger, and flying insect killer.
View Article and Find Full Text PDFPassive air sampling for nitrogen dioxide (NO(2)) and select volatile organic compounds (VOCs) was conducted at 24 fire stations and a compliance monitoring site in Dallas, Texas, USA during summer 2006 and winter 2008. This ambient air monitoring network was established to assess intra-urban gradients of air pollutants to evaluate the impact of traffic and urban emissions on air quality. Ambient air monitoring and GIS data from spatially representative fire station sites were collected to assess spatial variability.
View Article and Find Full Text PDFThe Brooklyn Traffic Real-Time Ambient Pollutant Penetration and Environmental Dispersion (B-TRAPPED) field study examined indoor and outdoor exposure to traffic-generated air pollution by studying the individual processes of generation of traffic emissions, transport and dispersion of air contaminants along a roadway, and infiltration of the contaminants into a residence. Real-time instrumentation was used to obtain highly resolved time-series concentration profiles for a number of air pollutants. The B-TRAPPED field study was conducted in the residential Sunset Park neighborhood of Brooklyn, NY, USA, in May 2005.
View Article and Find Full Text PDFOn August 29, 2005, Hurricane Katrina made landfall near New Orleans, Louisiana, a major metroplex with petroleum industries. In response to the potential impact of the storm on air quality and to assess the exposures to toxic air pollutants of public health concern, the United States Environmental Protection Agency conducted passive monitoring of air toxics for three months, starting in late October 2005 through early February 2006, at up to 18 sites in the New Orleans area affected by Hurricane Katrina. The overall results of the passive ambient monitoring are summarized with the concentrations for the twenty-nine observed volatile organic chemicals, which include benzene, toluene, ethylbenzene, and xylenes, and the measured concentrations are compared with available health-based screening levels.
View Article and Find Full Text PDFPassive ambient air sampling for nitrogen dioxide (NO(2)) and volatile organic compounds (VOCs) was conducted at 25 school and two compliance sites in Detroit and Dearborn, Michigan, USA during the summer of 2005. Geographic Information System (GIS) data were calculated at each of 116 schools. The 25 selected schools were monitored to assess and model intra-urban gradients of air pollutants to evaluate impact of traffic and urban emissions on pollutant levels.
View Article and Find Full Text PDFThis study evaluates performance of nitrogen dioxide (NO2) and volatile organic compound (VOC) passive samplers with corresponding reference monitors at two sites in the Detroit, Michigan area during the summer of 2005. Ogawa passive NO2 samplers and custom-made, re-useable Perkin-Elmer (PE) tubes with Carbopack X sorbent for VOCs were deployed under week-long sampling periods for six weeks. Precise results (5% relative standard deviation, RSD) were found for NO2 measurements from collocated Ogawa samplers.
View Article and Find Full Text PDFIn the summer of 2003, ambient air concentrations of volatile organic compounds (VOCs) were measured at 12 sites within a 3-km radius in Deer Park, Texas near Houston. The purpose of the study was to assess local spatial influence of traffic and other urban sources and was part of a larger investigation of VOC spatial and temporal heterogeneity influences in selected areas of Houston. Seventy 2-h samples were collected using passive organic vapor monitors.
View Article and Find Full Text PDFThe relationship between continuous measurements of volatile organic compounds sources and particle number was evaluated at a Photochemical Assessment Monitoring Station Network (PAMS) site located near the U.S.-Mexico Border in central El Paso, TX.
View Article and Find Full Text PDFThis study evaluates the performance of Model 3300 Ogawa Passive Nitrogen Dioxide (NO2) Samplers and 3M 3520 Organic Vapor Monitors (OVMs) by comparing integrated passive sampling concentrations to averaged hourly NO2 and volatile organic compound (VOC) measurements at two sites in El Paso, TX. Sampling periods were three time intervals (3-day weekend, 4-day weekday, and 7-day weekly) for three consecutive weeks. OVM concentrations were corrected for ambient pressure to account for higher elevation.
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