Structure-Activity Relationships in Oxygen Electrocatalysis.

Oxygen electrocatalysis, as the pivotal circle of many green energy technologies, sets off a worldwide research boom in full swing, while its large kinetic obstacles require remarkable catalysts to break through. Here, based on summarizing reaction mechanisms and in situ characterizations, the structure-activity relationships of oxygen electrocatalysts are emphatically overviewed, including the influence of geometric morphology and chemical structures on the electrocatalytic performances. Subsequently, experimental/theoretical research is combined with device applications to comprehensively summarize the cutting-edge oxygen electrocatalysts according to various material categories.

Advances and challenges in the electrochemical reduction of carbon dioxide.

The electrocatalytic carbon dioxide reduction reaction (ECORR) is a promising way to realize the transformation of waste into valuable material, which can not only meet the environmental goal of reducing carbon emissions, but also obtain clean energy and valuable industrial products simultaneously. Herein, we first introduce the complex CORR mechanisms based on the number of carbons in the product. Since the coupling of C-C bonds is unanimously recognized as the key mechanism step in the ECORR for the generation of high-value products, the structural-activity relationship of electrocatalysts is systematically reviewed.

Synergistic Promotion of Large-Current Water Splitting through Interfacial Engineering of Hierarchically Structured CoP-FeP Nanosheets with Rich P Vacancies.

The development of hydrogen evolution reaction (HER) catalysts with high performance under large current density is still a challenge. Introducing P vacancies in heterostructure is an appealing strategy to enhance HER kinetics. This study investigates a CoP-FeP heterostructure catalyst with abundant P vacancies (Vp-CoP-FeP/NF) on nickel foam (NF), which was prepared using dipping and phosphating treatment.

Nanowire-structured FeP-CoP arrays as highly active and stable bifunctional electrocatalyst synergistically promoting high-current overall water splitting.

The design and construction of highly efficient and durable non-noble metal bifunctional catalysts for oxygen evolution reaction (OER) and hydrogen evolution reaction (HER) in alkaline media is essential for developing the hydrogen economy. To achieve this goal, we have developed a bifunctional nanowire-structured FeP-CoP array catalyst on carbon cloth with uniform distribution through in-situ hydrothermal growth and phosphating treatment. The unique nanowire array structure and the strong electronic interaction between FeP and CoP species have been confirmed.

Interface Engineering of Needle-Like P-Doped MoS /CoP Arrays as Highly Active and Durable Bifunctional Electrocatalyst for Overall Water Splitting.

Developing a bifunctional water splitting catalyst with high efficiency and low cost are crucial in the electrolysis water industry. Here, we report a rational design and simple preparation method of MoS -based bifunctional electrocatalyst on carbon cloth (CC). The optimized P-doped MoS @CoP/CC catalyst presents low overpotentials for the hydrogen (HER) and oxygen evolution reactions (OER) of 64 and 282 mV in alkaline solution as well as 72 mV HER overpotential in H SO at a current density of 10 mA cm .