Enhancement of Selective Catalytic Oxidation of Lignin β-O-4 Bond via Orbital Modulation and Surface Lattice Reconstruction.

The orbital modulation and surface lattice reconstruction represent an effective strategy to regulate the interaction between catalyst interface sites and intermediates, thereby enhancing catalytic activity and selectivity. In this study, the crystal surface of Au-K/CeO catalyst can undergo reversible transformation by tuning the coordination environment of Ce, which enables the activation of the C-H bond and the oxidative cleavage of the C and C-C bonds, leading to the cleavage of 2-phenoxy-1-phenylethanol. The t orbitals of Au 5d hybridize with the 2p orbitals of lattice oxygen in CeO via π-coordination, modulating the coordination environment of Ce 4 f and reconstructing the lattice oxygen in the CeO framework, as well as increasing the oxygen vacancies.

Selective hydrogenation of vanillin over a graphene-encapsulated nitrogen-doped bimetallic magnetic Ni/Fe@NDC nano-catalyst.

One of the main obstacles to the development of sustainable biomass feedstocks today is the research of selective hydrogenation of biomass platform compounds for the synthesis of high-value chemicals. This work reports on the synthesis of a Ni/Fe bimetallic catalyst with nitrogen-doped carbon serving as the carrier, hydrogen serving as the primary donor, and isopropanol serving as the reaction medium and serving as a secondary donor. Vanillin was catalytically hydrogenated to produce 4-methylguaiacol, a complete hydrogenation product, under a reaction temperature of 200 °C for four hours.

Exploring carbohydrate extraction from biomass using deep eutectic solvents: Factors and mechanisms.

Deep eutectic solvents (DESs) are increasingly being recognized as sustainable and promising solvents because of their unique properties: low melting point, low cost, and biocompatibility. Some DESs possess high viscosity, remarkable stability, and minimal toxicity, enhancing their appeal for diverse applications. Notably, they hold promise in biomass pretreatment, a crucial step in biomass conversion, although their potential in algal biomass carbohydrates extraction remains largely unexplored.

Effects and Mechanisms of Cu Species in Fe-MOFs on Fenton-Like Catalytic Activity and Stability.

Fe-based MOFs (Fe-MOFs) are deemed promising Fenton-like catalysts due to their well-developed pores and accessible active sites. However, their inferior catalytic activity, iron leaching, and low HO utilization always hinder their application as Fe-based MOF catalysts. In this work, we manipulated the structure of Fe-oxo nodes in MIL-88B(Fe) via a Cu species substitution method, affording a mixed-valence (Cu-incorporated Fe-MOFs) with highly improved Fenton-like performance.

Pilot study on production of aviation fuel from catalytic conversion of corn stover.

Aviation fuel is high energy density and is usually produced from refinery in petroleum industry. Production of renewable aviation fuel from biomass eases pressure of carbon emission regulation. The operational processes in this study include steam stripping, hydrolysis of residues, condensation reaction unit, autoclave hydrogenation, fixed-bed hydrodeoxygenation, and oil-upgrading unit.

Ru-MnO Interaction for Efficient Hydrodeoxygenation of Levulinic Acid and Its Derivatives.

Metal-oxide interaction was widely observed in supported metal catalysts, playing a significant role in tuning the catalytic performance. Here, we reported that the interaction of Ru and MnO was able to facilitate the hydrodeoxygenation of levulinic acid (LA) to 2-butanol with a high turnover frequency (1.99 × 10 h), turnover number (4411), and yield (98.

Tungsten oxide decorated silica-supported iridium catalysts combined with HZSM-5 toward the selective conversion of cellulose to C alkanes.

Herein, WO-decorated Ir/SiO (W/Ir = 0.06) and HZSM-5 were coupled to selectively convert microcrystalline cellulose (MCC) into C alkanes. A 92.

Lefty A is involved in sunitinib resistance of renal cell carcinoma cells via regulation of IL-8.

Renal cell carcinoma (RCC) is the third most frequent malignancy within urological oncology. Sunitinib has been used as the standard of treatment for first-line RCC therapy. Understanding mechanisms of sunitinib resistance in RCC cell is important for clinical therapy and drug development.

Selective Hydrodeoxygenation of 5-Hydroxymethylfurfural to 2,5-Dimethylfuran over Ni Supported on Zirconium Phosphate Catalysts.

Crystal α-zirconium phosphate (α-ZrP) was prepared by a hydrothermal method and exfoliated into a layered structure by -hexylamine (CHNH). Ni-based catalyst (Ni/ZrP) was promoted by loading nickel on the layered α-ZrP via ion exchange. The catalyst was performed to catalyze hydrodeoxygenation of 5-hydroxymethylfurfural (HMF) to 2,5-dimethylfuran (DMF), and a 68.

Conversion of levulinic acid to γ-valerolactone over Ru/AlO-TiO catalyst under mild conditions.

Novel catalytic material with high catalytic activity and hydrothermal stability plays a key role in the efficient conversion of levulinic acid (LA) to γ-valerolactone (GVL) in water. In this study, mixed oxides AlO-TiO, AlO-MoO and AlO-CoO were synthesized by co-precipitation using aqueous solution of NaOH as precipitant. Ru catalysts supported on mixed oxides were prepared by impregnation method and their catalytic performances were tested in the hydrogenation of LA to GVL on a fixed bed reactor.

Hydrodeoxygenation of lignin-derived phenolic compounds to hydrocarbons over Ni/SiO2-ZrO2 catalysts.

Inexpensive non-sulfided Ni-based catalysts were evaluated for hydrodeoxygenation (HDO) using guaiacol as model compound. SiO2-ZrO2 (SZ), a complex oxide synthesized by precipitation method with different ratio of Si/Zr, was impregnated with Ni(NO3)2·6H2O and calcined at 500°C. Conversion rates and product distribution for guaiacol HDO at 200-340°C were determined.