Enhancing Adhesion Properties of Commodity Polymers through Thiol-Catechol Connectivities: A Case Study on Polymerizing Polystyrene-Telechelics via Thiol-Quinone Michael-Polyaddition.

Segmented block copolymers with adhesive functionality bridges in between are synthesized through the combination of controlled radical polymerization (CRP) and thiol-quinone Michael-polyaddition. CRP provides a set of α,ω-dithiol polystyrenes (PS), which react as telechelics with a low molecular weight bisquinone, resulting in thiol-catechol connectivities (TCCs). By introducing as little as 3 mol % of TCC functionalities, the bonding of the polymer on dry and wet aluminum surfaces is significantly improved while keeping the integrity of the PS segments undisturbed to constitute favorable bulk properties.

Implementing Zn ion and pH-value control into artificial mussel glue proteins by abstracting a His-rich domain from preCollagen.

A His-rich domain of preCollagen-D found in byssal threads is derivatized with Cys and Dopa flanks to allow for mussel-inspired polymerization. Artificial mussel glue proteins are accessed that combine cysteinyldopa for adhesion with sequences for pH or Zn2+ induced β-sheet formation. The artificial constructs show strong adsorption to Al2O3, the resulting coatings tolerate hypersaline conditions and cohesion is improved by activating the β-sheet formation, that enhances E-modulus up to 60%.