Luminescent Properties of β-(hydroxyaryl)-butenolides and Fluorescence Quenching in Water.

This work describes the luminescent properties of the new compound β-(hydroxyaryl)-butenolides recently discovered. The compounds were subjected to UV-Vis absorption and fluorescence analyzes when diluted in different solvents. Through the results, it was possible to observe that the β-hydroxyarylutenolides have two absorption bands, one at 289-291 nm and the other with higher intensity at 328-354 nm.

Intraspecific differentiation of sandflies specimens by optical spectroscopy and multivariate analysis.

Lutzomyia longipalpis and Lutzomyia cruzi are the main sandflies species involved in the transmission of Leishmania infantum protozoan in Brazil. The morphological characteristics can be used for species identification of males specimens, while females are indistinguishable. Although, sandflies identification is essential to understand vectorial capacity, and susceptibility to infectious agents or insecticides, there is a lack of new strategies for specimen identification.

True absolute determination of photoluminescence quantum yields by coupling multiwavelength thermal lens and photoluminescence spectroscopy.

Photoluminescence quantum yields denote a critical variable to characterise a fluorophore and its potential performance. Their determination, by means of methodologies employing reference standard materials, inevitably leads to large uncertainties. In response to this, herein we report for the first time an innovative and elegant methodology, whereby the use of neat solvent/reference material required by thermal lens approaches is eliminated by coupling it to photoluminescence spectroscopy, allowing for the discrimination between materials with similar photoluminescence quantum yields.

New approach to application of mid-infrared photoacoustic spectroscopy in forensic analysis: Study with the necrophagous blow fly Chrysomya megacephala (Diptera: Calliphoridae).

Insects can provide clues in a variety of ways to assist in criminal investigations. The FTIR-PAS technique has been successfully used to assess the cuticular chemical profiles of insect samples from different groups and for several goals. However, until now, it has never been used to evaluate samples of forensic interest, despite providing faster results, compared to the methods currently used.

In vitro and in vivo impact assessment of eco-designed CuO nanoparticles on non-target aquatic photoautotrophic organisms.

This work has assessed the impact of copper oxide nanoparticles (CuONPs), designed via green route, toward photosynthetic apparatus on aquatic photoautotrophic organisms. In order to filling knowledge gaps, in vitro and in vivo assays were performed, using cyanobacterial phycocyanin (C-PC) from Arthrospira platensis and Lemna valdiviana plants (duckweed), respectively. Impairment in light energy transfer became evident in C-PC exposed to CuONPs, giving rise to an increase of light absorption and a suppression of fluorescence emission.

Laser cooling of Yb:KYW.

We report the first observation of laser cooling in Yb:KYW and validate the results by comparison with experiments in the well-studied material Yb:YAG. Radiation from a single-mode Ti:AlO laser was used to achieve cooling of 1.5 K/W in 1% Yb:KYW at 1025 nm, comparing well with the reference material 3% Yb:YAG which cooled by 3.

Development of a Neutral Diketopyrrolopyrrole Phosphine Oxide for the Selective Bioimaging of Mitochondria at the Nanomolar Level.

Development of novel bioimaging materials that exhibit organelle specific accumulation continues to be at the forefront of research interests and efforts. Among the various subcellular organelles, mitochondria, which are found in the cytoplasm of eukaryotic cells, are of particular interest in relation to their vital function. To date, most molecular probes that target mitochondria utilise delocalised lipophilic cations such as triphenylphosphonium and pyridinium.

How does aquatic macrophyte Salvinia auriculata respond to nanoceria upon an increased CO source? A Fourier transform-infrared photoacoustic spectroscopy and chlorophyll a fluorescence study.

With the continued increase of technological uses of cerium oxide nanoparticles (CeO NPs or nanoceria) and their unregulated disposal, the accumulation of nanoceria in the environment is inevitable. Concomitantly, atmospheric carbon dioxide (CO) levels continue to rise, increasing the concentrations of bicarbonate ions in aquatic ecosystems. This study investigates the influence of CeO NPs (from 0 to 100 μgL) in the presence and absence of an elevated bicarbonate (HCO) ion concentration (1 mM), on vibrational biochemical parameters and photosystem II (PSII) activity in leaf discs of Salvinia auriculata.

Cytotoxic and genotoxic effects of silver nanoparticles on meristematic cells of Allium cepa roots: A close analysis of particle size dependence.

The use of silver nanoparticles (AgNPs) in commercial products has increased significantly in recent years. However, findings on the toxic effects of the AgNPs are still limited. This paper reports an investigation on the cytotoxic and genotoxic potential of the AgNPs on root cells of Allium cepa.

Polydomy in the ant Ectatomma opaciventre.

Tropical ants commonly exhibit a hyper-dispersed pattern of spatial distribution of nests. In polydomous species, nests may be satellites, that is, secondary structures of the main nest, where the queen is found. In order to evaluate whether the ant Ectatomma opaciventre Roger (Formicidae: Ectatomminae) uses the strategy of building polydomous nests, the spatial distribution pattern of 33 nests in a 1,800 m(2) degraded area located in Rio Claro, SP, Brazil, were investigated using the nearest neighbor method.

Differentiation of neotropical fish species with statistical analysis of fourier transform infrared photoacoustic spectroscopy data.

Fourier transform infrared photoacoustic spectroscopy (FTIR-PAS) was applied to nineteen fish species in Brazil's Upper Paraná River basin to identify differences in the structural composition of their scales. To differentiate the species, a canonical discriminant analysis was used to indicate the most important absorption peaks in the mid-infrared region. Significant differences were found in the chemical composition of scales among the studied fish species, with Wilk's lambda = 5.

Determination of the biodiesel content in diesel/biodiesel blends: a method based on fluorescence spectroscopy.

Blends of biodiesel and diesel are being used increasingly worldwide because of environmental, economic, and social considerations. Several countries use biodiesel blends with different blending limits. Therefore, it is necessary to develop or improve methods to quantify the biodiesel level in a diesel/biodiesel blend, to ensure compliance with legislation.