Oxidative Lipidomics to Unravel the Glycerol Core Aldehydes of Three Typical Unsaturated Triglycerides under Simulated Heating Conditions.

Glycerol core aldehydes (GCAs) are significant nonvolatile aldehyde compounds generated in heated edible oils, which may pose potential health risks. Utilizing the complementary CID and EAD mass spectrometry data, this study introduced a predict-to-hit strategy, identifying 42 types of GCAs from oxidized OOO, LLL, and LnLnLn. Structural analysis revealed that oxidation occurred at both the sn-2 and sn-1/3 positions of triglyceride (TG), with the Sn-1/3 position exhibiting greater susceptibility as the degree of TG unsaturation increased.

Terahertz Spectroscopic Identification of Roast Degree and Variety of Coffee Beans.

In this study, terahertz time-domain spectroscopy (THz-TDS) was proposed to identify coffee of three different varieties and three different roasting degrees of one variety. Principal component analysis (PCA) was applied to extract features from frequency-domain spectral data, and the extracted features were used for classification prediction through linear discrimination (LD), support vector machine (SVM), naive Bayes (NB), and k-nearest neighbors (KNN). The classification effect and misclassification of the model were analyzed via confusion matrix.

Studies on qualitative and quantitative detection of trehalose purity by terahertz spectroscopy.

Terahertz spectroscopy was used to qualitatively and quantitatively analyze four samples (three brands) of trehalose produced in China and other countries. The results show that the main characteristic peak was greatly affected by concentration, and the optimal detection concentration of trehalose was determined to be 25%-55% by transmission scanning. There were six significant characteristic absorption peaks in the trehalose spectrum, meaning that terahertz spectroscopy can be used for qualitative analysis, analogous to infrared spectroscopy.

Full-time response of starch subjected to microwave heating.

The effect of non-ionizing microwave radiation on starch is due to a gelatinization temperature range that changes starch structure and properties. However, the changes in starch upon microwave heating are observable throughout the heating process. We compared the effects on starch heating by microwaves to the effects by rapid and regular conventional heating.

Effects of the components in rice flour on thermal radical generation under microwave irradiation.

The relationships between radical generation under microwave irradiation and the components of various types of rice flour were investigated. Electron paramagnetic resonance (EPR) spectroscopy was used to characterize the radicals found in rice flour samples. The EPR spectra revealed that several types of radical (carbon-centered, tyrosyl and semiquinone) were localized in the starch and protein fractions of the rice flour.

The influence of metal ions on the dielectric enhancement and radical generation of rice starch during microwave processing.

In this study, the effect of the enrichment of rice starch with metal ions on its capability to generate free radicals during microwave processing was investigated. The underlying mechanism was explored from two aspects: dielectric and thermal properties. Rice starch was modified with ions of iron, copper, manganese and calcium.

Influence of microwave parameters and water activity on radical generation in rice starch.

Radical generation in rice starch under microwave treatment as well as the related chemical bond changes were investigated by electron paramagnetic resonance (EPR) and Raman spectroscopy. Samples with water activity of 0.4 and 0.

Study of the optimisation of puffing characteristics of potato cubes by spouted bed drying enhanced with microwave.

Background: In commercial deep-fat frying of potato chips, the oil content of the final products ranges from 35 to 45 g 100 g(-1) (wet basis). High-temperature frying may cause the formation of acrylamide, making the products unhealthy to the consumer. The aim of this research was to explore a new method, spouted bed microwave drying, to produce healthier puffed snack potato cubes as possible alternatives to oil-fried potato chips.